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AgCl dissolved in excess of NH(3), KCN a...

`AgCl` dissolved in excess of `NH_(3), KCN` and `Na_(2)S_(2)O_(3)` solutions the complex produces ions

A

`[Ag(NH_(3))_(2)]^(+), [Ag(CN)_(2)]^(-) & [Ag(S_(2)O_(3))_(2)]^(3-)`

B

`[Ag(NH_(2))_(2)]^(2+), [Ag(CN)_(2)]^(3-) & [Ag_(4) (S_(2)O_(3))_(5)]^(2+)`

C

`[Ag(NH_(3))_(2)]^(2+), [Ag(CN)_(2)]^(+) & [Ag_(2) (S_(2)O_(3))_(2)]^(2-)`

D

`[Ag(NH_(3))_(4)]^(+), [Ag(CN)_(4)]^(3-) & [Ag_(2) (S_(2)O_(3))_(2)]^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
A

`EAN =Z-x+n xx y`, Z=At number of metal ion, x=charge of metal ion, n=secondary valency
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NARAYNA-CO-ORDINATE COMPOUNDS -Exercise -1 (H.W.)
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  11. For the given complex [CoCl(2)(en)(NH(3))(2)]^(+), the number of geome...

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  12. Which does not obey EAN rule?

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