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Which of the following will give a pair ...

Which of the following will give a pair of enontiomorphs ?
`en = NH_(2)CH_(2)CH_(2)NH_(2)`

A

`[Co(NH_(3))_(4)Cl_(2)]NO_(2)`

B

`[Cr(NH_(3))_(6)] [Co(CN)_(6)]`

C

`[Co(en)_(2) Cl_(2)] Cl`

D

`[Pt (NH_(3))_(4) ] [PtCl_(6)]`

Text Solution

Verified by Experts

The correct Answer is:
C

A pair of molecules related to each other as an object and its mirror image are known as enantiomorphs or enantiomers. These are not supermposble on their mirror image.
`[Co(en)_(2)Cl_(2)]^(+)` Dichlorobis (ethylene diamine) cobalt (III) is therefore, enantiomorphs.
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Knowledge Check

  • Which of the following is a gas at room temperature ? CH_(3)NH_(2) (ii) CH_(3)CH_(2)NH_(2) (iii) (CH_(3))_(2) (iv) (CH_(3))_(3)N

    A
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    B
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    D
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  • Which of the following complexes can exhibit optical isomerism? (e n=H_(2)N-CH_(2)-CH_(2)-NH_(2))

    A
    `cis-[Co(NH_(3))_(4)Cl_(2)]`
    B
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    C
    `cis-[Co(en)_(2)Cl_(2)]`
    D
    trans `-[Co(en)_(2)Br_(2)]`
  • The ligand N(CH_(2)CH_(2)NH_(2))_(3) is

    A
    tridentate
    B
    pentadentate
    C
    tetradentate
    D
    bidentate
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