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AgCl dissolved in excess of NH(3), KCN a...

`AgCl` dissolved in excess of `NH_(3), KCN` and `Na_(2)S_(2)O_(3)` solutions the complex produces ions

A

`[Ag(NH_(3))^(2+), [Ag(CN)_(2)]^(+) and [Ag(S_(2)O_(3))_(2)]^(3-)` \

B

`[Ag(NH_(3))_(2)]^(2+), [Ag(CN)_(2)]^(3-) and [Ag(S_(2)O_(3))_(2)]^(2-)`

C

`[Ag(NH_(3))_(4)]^(2+), [Ag(CN)_(2)]^(3-) and [Ag(S_(2)O_(3))_(2)]^(2-)`

D

`[Ag(NH_(3))_(2)]^(+), [Ag(CN)_(2)]^(-) and [Ag(S_(2)O_(3))_(2)]^(3-)`

Text Solution

Verified by Experts

The correct Answer is:
D
`AgCl+2NH_(3) to [Ag(NH_(3))_(2)]Cl`
`AgCl+2KCN to K[Ag(CN)_(2)]+KCl`
`AgCl+2Na_(2)S_(2)O_(3) to Na_(3) [Ag(S_(2)O_(3))_(2)]^(3-)`
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NARAYNA-CO-ORDINATE COMPOUNDS -Exercise-3
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  14. Among the following complexes, the one which shows zero crystal field ...

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  15. The name of complex ion, [Fe(CN(6))]^(3-) is

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