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The d-electron configurations of Cr^(2+)...

The d-electron configurations of `Cr^(2+), Mn^(2+), Fe^(2+)` and `Co^(2+)` are `d^4, d^5, d^6` and `d^7` respectively. Which one of the following will exhibit minimum paramagnetic behavious?

A

`[Cr(H_(2)O)_(6)]^(2+)`

B

`[Mn(H_(2)O)_(6)]^(2+)`

C

`[Fe(H_(2)O)_(6)]^(+2)`

D

`[Co(H_(2)O)_(6)]^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
D

`Co^(2+) to 3d^(7), 4s^(0)`
: having minimum no. of unpaired electrons.
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NARAYNA-CO-ORDINATE COMPOUNDS -Exercise-3
  1. Choose the correct statement

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  2. In the complex ion [CoNH(3))(6)]^(3+) , the NH(3) molecules are li...

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  3. The d-electron configurations of Cr^(2+), Mn^(2+), Fe^(2+) and Co^(2+)...

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  4. Of the following complex ions, which is diamagnetic in natures?

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  5. The comlexes [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6] are the exa...

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  6. The complex, [Pt(py)(NH3)BrCl] will have how many geometrical isomers?

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  7. From four transition metal octahedral complexes , (the choice g...

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  8. Which one of the following is an outer orbital complex and exhibits pa...

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  9. A magnetic moment of 1.73 B.M. will be shown by one among the followin...

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  10. Among the following complexes, the one which shows zero crystal field ...

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  11. The name of complex ion, [Fe(CN(6))]^(3-) is

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  12. The hybridization involved in complex [Ni(CN)(4)]^(2-) is (At. No . Ni...

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  13. The sum of coordination number and oxidation number of the metal M in ...

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  14. Number of possible isomer for the complex [Co(en)(2)CI(2)]CI will be: ...

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  15. Cobalt (III) chloride forms several octahedral complexes with amonia. ...

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  16. Which of the following has longest [CO(CN)(6)]^(3-) bond length?

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  17. Which of the following has longest C-O bond length? (Free C-O bond len...

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  18. The correct increasing order of trans-effect of the following species ...

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  19. Jahn - Teller effect is not observed in high spin complexes of

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  20. AIF(3) is soluble in HF only in presence of KF. It is due to the forma...

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