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(CH(3))(2) CO underset((HCl))overset("Na...

`(CH_(3))_(2) CO underset((HCl))overset("NaCN")(rarr) A underset(Delta)overset(H_(3)O^(+))(rarr) B` In the above sequence of reactions A and B are

A

`(CH_(3))_(2)` C (OH)CN, `(CH_(3))_(2)` C(OH)COOH

B

`(CH_(3))_(2)` C(OH)CN, `(CH_(3))_(2) C(OH)_(2)`

C

`(CH_(3))_(2)`C(OH)CN, `(CH_(3))_(2)` CHCOOH

D

`(CH_(3))_(2)` C(OH)CN, `(CH_(3))_(2)` C = O

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the compounds A and B in the given reaction sequence. Let's break it down step by step. ### Step 1: Identify the starting compound The starting compound is (CH₃)₂CO, which is acetone. ### Step 2: Reaction with HCl and NaCN When acetone reacts with HCl, it forms a protonated intermediate. The presence of NaCN indicates that a nucleophilic addition reaction will occur. The cyanide ion (CN⁻) acts as a nucleophile and attacks the carbonyl carbon of acetone. ### Step 3: Formation of compound A The nucleophilic attack leads to the formation of a cyanohydrin. The structure of compound A can be represented as follows: - The carbonyl group (C=O) is converted into a hydroxyl group (C-OH) and a cyanide group (C≡N) is added to the carbon. - Therefore, compound A is (CH₃)₂C(OH)CN, which can be written as CH₃C(OH)(CN)CH₃. ### Step 4: Acidic hydrolysis of compound A Next, compound A undergoes acidic hydrolysis (indicated by Δ and H₃O⁺). During this process, the cyanide group (CN) is converted into a carboxylic acid (COOH). - The reaction replaces the CN group with a COOH group, leading to the formation of compound B. ### Step 5: Formation of compound B The structure of compound B is: - The cyanide group (CN) in compound A is replaced by a carboxylic acid group (COOH). - Thus, compound B is (CH₃)₂C(OH)COOH, which can be written as CH₃C(OH)COOHCH₃. ### Conclusion - Compound A is (CH₃)₂C(OH)CN (a cyanohydrin). - Compound B is (CH₃)₂C(OH)COOH (a carboxylic acid). ### Final Answer - A: (CH₃)₂C(OH)CN - B: (CH₃)₂C(OH)COOH
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