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o-xylene when oxidised in presence of ai...

o-xylene when oxidised in presence of air and `(CH_(3)"COO")_(2)` Mn eatalyst gives which of the following product ?

A

Benzoic acid

B

Phenyl acetic acid

C

Phthalic acid

D

Acetic acid

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AI Generated Solution

The correct Answer is:
To solve the problem of what product is formed when o-xylene is oxidized in the presence of air and a manganese acetate catalyst, we can follow these steps: ### Step 1: Understand the Structure of o-Xylene o-Xylene is a dimethylbenzene where two methyl groups (-CH₃) are attached to the benzene ring at the 1 and 2 positions (ortho position). Its structure can be represented as follows: ``` CH3 | C6H4--C--CH3 ``` ### Step 2: Identify the Oxidation Process When o-xylene is oxidized, the methyl groups are converted into carboxylic acid groups (-COOH). This oxidation typically occurs under high temperatures and pressures in the presence of an oxidizing agent. ### Step 3: Set the Reaction Conditions The reaction conditions provided are: - Temperature: 175 to 225 degrees Celsius - Pressure: 15 to 30 atm of O₂ - Catalyst: Manganese acetate (CH₃COO)₂Mn ### Step 4: Predict the Products Under these conditions, both methyl groups of o-xylene will be oxidized to form carboxylic acid groups. Therefore, the product will be phthalic acid, which is a 1,2-dicarboxylic acid. The structure of phthalic acid is: ``` COOH | C6H4--C--COOH ``` ### Step 5: Conclusion The final product of the oxidation of o-xylene under the given conditions is phthalic acid. Thus, the correct answer is **phthalic acid**. ---

To solve the problem of what product is formed when o-xylene is oxidized in the presence of air and a manganese acetate catalyst, we can follow these steps: ### Step 1: Understand the Structure of o-Xylene o-Xylene is a dimethylbenzene where two methyl groups (-CH₃) are attached to the benzene ring at the 1 and 2 positions (ortho position). Its structure can be represented as follows: ``` CH3 | ...
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  7. Two moles of acetic acid are heated with P(2)O(5). The product formed ...

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  8. o-xylene when oxidised in presence of air and (CH(3)"COO")(2) Mn eatal...

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  9. In esterification, OH^(-) Ion for making comes from

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  11. The vapure of a carboxylic acid HA when passed over MnO at 573 Kyields...

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  14. Which CH(3)COOH reacts with CH(3)-MgX, then

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  15. Base hydrolysis of an ester with NaOH gives a carboxylic acid whose so...

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  16. Acetic anhydride reacts with excess of ammonia to from

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  17. In the reaction CH(3)COOHoverset(LiAlH(4))rarr(A)overset(I(2)+NaOH)r...

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  20. Benzoic acid has higher molecular weight in benzene and lesser molecul...

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