Home
Class 12
CHEMISTRY
Acetaldehyde on treatment with HCN forms...

Acetaldehyde on treatment with HCN forms a cyanohydrin. What will be the product if this cyanohydrin is further hydrolysed ?

A

`CH_(3)`COOH

B

C

D

`CH_(3) CH_(2)`OH

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to follow these steps: ### Step 1: Understand the Reactants We start with acetaldehyde, which has the chemical structure CH3CHO. Acetaldehyde is an aldehyde, and when it reacts with hydrogen cyanide (HCN), it will form a cyanohydrin. ### Step 2: Reaction with HCN In the presence of HCN, the cyanide ion (CN⁻) acts as a nucleophile and attacks the electrophilic carbon atom of the carbonyl group in acetaldehyde. This leads to the formation of a cyanohydrin. The reaction can be represented as follows: \[ \text{CH}_3\text{CHO} + \text{HCN} \rightarrow \text{CH}_3\text{C(OH)(CN)} \] This product is known as 2-cyanoethanol. ### Step 3: Hydrolysis of the Cyanohydrin Next, we need to consider what happens when the cyanohydrin undergoes hydrolysis. Hydrolysis involves the addition of water (H2O) to the cyanohydrin, which will convert the cyano group (CN) into a carboxylic acid (COOH). The hydrolysis reaction can be represented as follows: \[ \text{CH}_3\text{C(OH)(CN)} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{C(OH)(COOH)} \] ### Step 4: Final Product After hydrolysis, the cyanohydrin will yield the corresponding carboxylic acid. In this case, the product will be: \[ \text{CH}_3\text{COOH} \] which is acetic acid. ### Conclusion Thus, the final product after hydrolysis of the cyanohydrin formed from acetaldehyde and HCN is acetic acid (CH3COOH).

To solve the question, we need to follow these steps: ### Step 1: Understand the Reactants We start with acetaldehyde, which has the chemical structure CH3CHO. Acetaldehyde is an aldehyde, and when it reacts with hydrogen cyanide (HCN), it will form a cyanohydrin. ### Step 2: Reaction with HCN In the presence of HCN, the cyanide ion (CN⁻) acts as a nucleophile and attacks the electrophilic carbon atom of the carbonyl group in acetaldehyde. This leads to the formation of a cyanohydrin. ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • ALDEHYDES, KETONES & CARBOXYLIC ACIDS

    NARAYNA|Exercise EXERCISE -I (H.W.)|15 Videos
  • ALDEHYDES, KETONES & CARBOXYLIC ACIDS

    NARAYNA|Exercise EXERCISE -II (C.W.)|25 Videos
  • ALDEHYDES, KETONES & CARBOXYLIC ACIDS

    NARAYNA|Exercise C.U.Q|60 Videos
  • ALCOHOLS, ETHERS, PHENOL

    NARAYNA|Exercise Assertion Reaosn|10 Videos
  • AMINES & DIAZO COMPOUNDS

    NARAYNA|Exercise Subjective type Q.|13 Videos

Similar Questions

Explore conceptually related problems

What is meant by cyanohydrin ?

What is the product formed in the reaction?

Knowledge Check

  • An aldehyde reacts with KCN to form cyanohydrin. In this reaction

    A
    `CN^-` acts as nucleophile and does nucleophilic addition
    B
    `CN^-` acts as nucleophile and does electrophilic addition
    C
    `CN^-` acts as an electrophilic and does electrophilic addition
    D
    `CN^-` acts as nuclcophile and does nucleophile substitution
  • What will be the product formed in the above reaction ?

    A
    B
    C
    D
  • The product/s formed when diborane is hydrolysed

    A
    `B_(2)O_(3)` and `H_(3)BO_(3)`
    B
    `B_(2)O_(3)` only
    C
    `H_(3)BO_(3)` and `H_(2)`
    D
    `H_(3)BO_(3)` only
  • Similar Questions

    Explore conceptually related problems

    What is the product formed in the following reaction.

    What would be the product when acetaldehyde reacts with HCN and the product is further hydrolysed-

    Acetaldehyde and acetone react with HCN to form corresponding __________.

    What is the product when acetylene reacts with HCN

    Chlorobenzene on treatment with acetyl chloride and anhydrous AlCl_3 the major product formed will be