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In the reaction sequence : C(6)H(5) CH...

In the reaction sequence :
`C_(6)H_(5) CHO overset("HCN")(rarr) [X] overset(H_(2)O // H^(oplus))(rarr)`product
Product will be :

A

Optically inactive acid

B

Optically active `alpha` - hydroxy acid

C

Racemic mixture of two optically in active primary alcohols

D

Racemic mixture of two optically active primary alcohols

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given problem, we will analyze the reaction sequence step by step. ### Step 1: Identify the initial compound The starting compound is **C₆H₅CHO**, which is benzaldehyde. It consists of a benzene ring (C₆H₅) attached to a formyl group (CHO). ### Step 2: Reaction with HCN When benzaldehyde reacts with hydrogen cyanide (HCN), it undergoes a nucleophilic addition reaction. The cyanide ion (CN⁻) attacks the carbonyl carbon of the aldehyde, leading to the formation of a cyanohydrin. **Reaction:** \[ \text{C}_6\text{H}_5\text{CHO} + \text{HCN} \rightarrow \text{C}_6\text{H}_5\text{C(OH)(CN)} \] Here, the product formed is a cyanohydrin, which has a hydroxyl group (OH) and a cyanide group (CN) attached to the same carbon. ### Step 3: Hydrolysis of the cyanohydrin The next step involves the hydrolysis of the cyanohydrin in the presence of water (H₂O) and an acid (H⁺). During hydrolysis, the cyanide group (CN) is converted into a carboxylic acid (COOH). **Reaction:** \[ \text{C}_6\text{H}_5\text{C(OH)(CN)} + \text{H}_2\text{O} \xrightarrow{\text{H}^+} \text{C}_6\text{H}_5\text{COOH} + \text{NH}_4\text{OH} \] The final product is **benzoic acid (C₆H₅COOH)**. ### Final Answer The product formed after the complete reaction sequence is **benzoic acid (C₆H₅COOH)**. ---

To solve the given problem, we will analyze the reaction sequence step by step. ### Step 1: Identify the initial compound The starting compound is **C₆H₅CHO**, which is benzaldehyde. It consists of a benzene ring (C₆H₅) attached to a formyl group (CHO). ### Step 2: Reaction with HCN When benzaldehyde reacts with hydrogen cyanide (HCN), it undergoes a nucleophilic addition reaction. The cyanide ion (CN⁻) attacks the carbonyl carbon of the aldehyde, leading to the formation of a cyanohydrin. ...
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NARAYNA-ALDEHYDES, KETONES & CARBOXYLIC ACIDS-EXERCISE -II (C.W.)
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  2. In the reaction sequence : C(6)H(5) CHO overset("HCN")(rarr) [X] ove...

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  3. In the given reaction : Carbonyl compound, C(8) H(16) O [X] overset...

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  4. In the reaction X + Y underset(5^(@)C)overset(NaOH)(rarr) CH(3)-ov...

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  5. In the reaction : [X] will be :

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  6. In the given reaction CH(3)-CH(2)-COOHunderset((ii)." "Br(2)//Delta)ov...

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  7. In the given reaction :

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  8. In the given reaction CH(3)-COOH underset(underset("(iii) "H(2)O //H^(...

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  9. In the given reactions :

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  10. The reduction of benzoyl chloride with H(2)//Pd-BaSO(4) produces

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  11. Which reaction can produce R - CO-Ar species :

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  12. Which one is a mixed ketone :

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  13. Hydrolysis of an ester gives a carboxylic acid which on Kolbe's electr...

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  14. Reaction of aniline with acety1 chloride in the presence of NaOH gives...

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  15. m-chlorobenzaldehyde on reaction with conc. KOH at room temperature gi...

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  16. In Etard's reaction toluene is oxidised to benzaldehyde using

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  17. Which of the following does not give brick red ppt. with Fehling solut...

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  18. The organic product formed in the reaction C(6) H(5)"COOCH"(3) under...

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  19. The class of compounds that are reduced to primary alcohols and also r...

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  20. Benzoic acid with "SOCl"(2) to give

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