The organic product formed in the reaction
`C_(6) H_(5)"COOCH"_(3) underset((ii)H_(2)O)overset((i)"LiAlH"_(4))(rarr)`

Options

A. `C_(6)H_(5) CH_(2)`OH and `CH_(3)`OH
B. `C_(6) H_(5)`COOH and `CH_(4)`
C. `C_(6) H_(5)CH_(3) and CH_(3)` OH
D. `C_(6) H_(5)CH_(3) and CH_(4)`

Explanation

To determine the organic product formed in the reaction of `C6H5COOCH3` with `LiAlH4` followed by hydrolysis with water, we can follow these steps:

### Step 1: Identify the Reactants
The reactant is `C6H5COOCH3`, which is methyl benzoate. It contains a phenyl group (C6H5) attached to a carbonyl group (C=O) and an ether group (O-CH3).

### Step 2: Understand the Role of Lithium Aluminum Hydride (LiAlH4)
Lithium Aluminum Hydride is a strong reducing agent. It can reduce esters, aldehydes, and ketones to their corresponding alcohols. In this case, it will reduce the ester (methyl benzoate) to an alcohol.

### Step 3: Reduction Reaction
When methyl benzoate reacts with `LiAlH4`, the carbonyl carbon (C=O) of the ester is reduced. The reaction can be represented as follows:

1. The carbonyl oxygen is attacked by the hydride ion (H-) from `LiAlH4`.
2. This leads to the formation of a tetrahedral intermediate.
3. The intermediate collapses, resulting in the formation of benzyl alcohol (`C6H5CH2OH`) and methanol (`CH3OH`).

### Step 4: Hydrolysis
After the reduction, the reaction mixture is treated with water (H2O). This step is necessary to protonate the alkoxide intermediate formed during the reduction, converting it into the alcohol form.

### Step 5: Final Products
The final products of the reaction are:
- Benzyl alcohol (`C6H5CH2OH`)
- Methanol (`CH3OH`)

### Conclusion
The organic products formed from the reaction of `C6H5COOCH3` with `LiAlH4` followed by hydrolysis with water are benzyl alcohol and methanol.

---