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Identify X, H(3)C - overset(CH(3))over...

Identify X,
`H_(3)C - overset(CH_(3))overset(|)(C ) = O underset("dry ether")overset(CH_(3)"Mgl")(rarr) A overset(H_(2)O)(rarr)`X,

A

`CH_(3)OH`

B

`CH_(3)CH_(2)`OH

C

`CH_(3)"CHOHCH"_(3)`

D

`CH_(3)"C(OH)"(CH_(3))_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify the compound X formed from the reaction of a ketone with a Grignard reagent followed by hydrolysis. Let's break it down step by step. ### Step 1: Identify the starting compound We start with a ketone represented as: \[ \text{H}_3\text{C} - \text{C}(=O) - \text{C}(\text{CH}_3) \] This ketone has two methyl groups (CH₃) attached to the carbonyl carbon. ### Step 2: Reaction with Grignard reagent The Grignard reagent given is: \[ \text{CH}_3\text{MgI} \] In this reaction, the nucleophilic carbon from the Grignard reagent (CH₃⁻) will attack the electrophilic carbonyl carbon of the ketone. The reaction can be represented as: \[ \text{H}_3\text{C} - \text{C}(=O) - \text{C}(\text{CH}_3) + \text{CH}_3\text{MgI} \rightarrow \text{A} \] ### Step 3: Formation of the intermediate (A) When the nucleophile attacks, the carbonyl group (C=O) will be converted into an alcohol group (C-OH), and we will have: \[ \text{A} = \text{H}_3\text{C} - \text{C}(\text{OH}) - \text{C}(\text{CH}_3)(\text{CH}_3) \] This means that the intermediate A will have a tertiary alcohol structure. ### Step 4: Hydrolysis of the intermediate Now, we perform hydrolysis on compound A. Hydrolysis involves the addition of water, which will convert the magnesium alkoxide into a hydroxyl group: \[ \text{A} + \text{H}_2\text{O} \rightarrow \text{X} \] ### Step 5: Identify the final product (X) After hydrolysis, the final product X will be: \[ \text{X} = \text{H}_3\text{C} - \text{C}(\text{OH}) - \text{C}(\text{CH}_3)(\text{CH}_3) \] This compound is a tertiary alcohol with the structure: \[ \text{X} = \text{2-methyl-2-butanol} \] ### Final Answer Thus, the compound X is 2-methyl-2-butanol. ---

To solve the problem, we need to identify the compound X formed from the reaction of a ketone with a Grignard reagent followed by hydrolysis. Let's break it down step by step. ### Step 1: Identify the starting compound We start with a ketone represented as: \[ \text{H}_3\text{C} - \text{C}(=O) - \text{C}(\text{CH}_3) \] This ketone has two methyl groups (CH₃) attached to the carbonyl carbon. ### Step 2: Reaction with Grignard reagent ...
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NARAYNA-ALDEHYDES, KETONES & CARBOXYLIC ACIDS-EXERCISE -II (C.W.)
  1. In the given reaction CH(3)-CH(2)-COOHunderset((ii)." "Br(2)//Delta)ov...

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  2. In the given reaction :

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  3. In the given reaction CH(3)-COOH underset(underset("(iii) "H(2)O //H^(...

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  4. In the given reactions :

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  5. The reduction of benzoyl chloride with H(2)//Pd-BaSO(4) produces

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  6. Which reaction can produce R - CO-Ar species :

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  7. Which one is a mixed ketone :

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  8. Hydrolysis of an ester gives a carboxylic acid which on Kolbe's electr...

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  9. Reaction of aniline with acety1 chloride in the presence of NaOH gives...

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  10. m-chlorobenzaldehyde on reaction with conc. KOH at room temperature gi...

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  11. In Etard's reaction toluene is oxidised to benzaldehyde using

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  12. Which of the following does not give brick red ppt. with Fehling solut...

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  13. The organic product formed in the reaction C(6) H(5)"COOCH"(3) under...

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  14. The class of compounds that are reduced to primary alcohols and also r...

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  15. Benzoic acid with "SOCl"(2) to give

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  16. Identify X in the sequence, X underset(2H(2)O //H^(+))overset(1.CH(3...

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  17. Identify X, H(3)C - overset(CH(3))overset(|)(C ) = O underset("dry e...

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  18. Pick out the reaction in which formic and acetic acids differs from ea...

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  19. The most acidic among the following is

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  20. Select the strongest acid :

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