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In the following reactions, (a) H(3)C...

In the following reactions,
(a) `H_(3)C-overset(CH_(3))overset("| ")(CH)-underset(" "OH )underset(|)(CH)-CH_(3)overset(H^(+)//heat)rarr underset("product")underset("Major")(A) + underset("product")underset("Minor")(B)`
(b) `A overset(HBr,dark)underset("in absence of peroxide")rarr underset("product")underset("Major")(C)+underset("product")underset("Minor")(D)`
The major products (A) and (C) are respectively:

A

`CH_(3) - overset(CH_(3))overset(|)(C ) = CH - CH_(3)` and `CH_(3) - overset(CH_(3))overset(|)(CH) - underset(Br) underset(|)(CH) - CH_(3)`

B

`CH_(2) = overset(CH_(3))overset(|)(C ) - CH_(2) - CH_(3)` and `CH_(3) - underset(Br) underset(|)overset(CH_(3))overset(|)(C) - CH_(2) - CH_(3)`

C

`CH_(2) = overset(CH_(3))overset(|)(C ) - CH_(2) - CH_(3)` and `underset(Br) underset(|)(CH_(2))-overset(CH_(3)) overset(|)(CH) - CH_(2) - CH_(3)`

D

`CH_(3) - overset(CH_(3))overset(|)(C ) = CH - CH_(3)` and `CH_(3) - underset(Br)underset(|)overset(CH_(3))overset(|)(C ) - CH_(2) - CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
D

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