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A compound (X) C(4)H(8)O Which gives a 2...

A compound (X) `C_(4)H_(8)`O Which gives a 2,4-DNP derivative and a positive iodoform test is:

A

`CH_(3) -CH_(2) - overset(O)overset(||)(C ) - CH_(3)`

B

`CH_(3) - CH_(2) -CH_(2)-`CHO

C

`CH_(3)- underset(CH_(3))underset(|)(CH) -`CHO

D

All of these

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The correct Answer is:
To solve the problem, we need to identify the compound (X) with the molecular formula C4H8O that gives a 2,4-DNP derivative and a positive iodoform test. Let's break down the steps: ### Step 1: Analyze the Molecular Formula The compound has the molecular formula C4H8O. This indicates that it could be either a ketone or an aldehyde. **Hint:** Look for functional groups that can fit the molecular formula C4H8O. ### Step 2: Identify the Functional Groups Since the compound gives a positive iodoform test, it must contain a methyl ketone group (–COCH3). This is a key requirement for the iodoform test, which is positive for compounds that have the structure RCOCH3, where R can be any alkyl group. **Hint:** Remember that the iodoform test is specific for methyl ketones. ### Step 3: Determine Possible Structures Given that the compound is C4H8O and must contain a methyl ketone, we can deduce that the structure must be a ketone. The possible structure that fits this description is 3-pentanone (or 2-butanone), which has the methyl group adjacent to the carbonyl group. **Hint:** Draw out possible structures for C4H8O that include a methyl ketone. ### Step 4: Confirm the 2,4-DNP Test The 2,4-DNP (2,4-dinitrophenylhydrazine) test is used to identify carbonyl compounds (aldehydes and ketones). When a ketone or aldehyde reacts with 2,4-DNP, it forms a yellow-orange precipitate. Since we have identified that our compound is a ketone, it will react with 2,4-DNP to form a derivative. **Hint:** Recall that the formation of a yellow-orange precipitate indicates the presence of a carbonyl group. ### Step 5: Conclusion Based on the above analysis, the compound (X) is likely to be 2-butanone (or 3-pentanone) since it meets all the criteria: it has the molecular formula C4H8O, gives a positive iodoform test due to the presence of a methyl ketone, and forms a 2,4-DNP derivative. **Final Answer:** The compound (X) is 2-butanone (or 3-pentanone).

To solve the problem, we need to identify the compound (X) with the molecular formula C4H8O that gives a 2,4-DNP derivative and a positive iodoform test. Let's break down the steps: ### Step 1: Analyze the Molecular Formula The compound has the molecular formula C4H8O. This indicates that it could be either a ketone or an aldehyde. **Hint:** Look for functional groups that can fit the molecular formula C4H8O. ### Step 2: Identify the Functional Groups ...
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NARAYNA-ALDEHYDES, KETONES & CARBOXYLIC ACIDS-EXERCISE -4
  1. The correct order of reactivity of PhMgBr with Ph - overset(O)overse...

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  2. A compound (A) C(5)H(10) Cl(2) on hydrolysis gives C(5)H(10)O which re...

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  3. Predict the product in the following reaction

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  4. What is X ?

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  5. Which one of the following compounds on heating with a base gives as t...

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  6. End product of following sequence of reaction

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  7. The formation of cyanohydrin from ketone is an example of :

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  8. A compound (X) C(4)H(8)O Which gives a 2,4-DNP derivative and a positi...

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  9. Which one of the following structure is not an isomer of the compound ...

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  10. Which carbonyl group of the given compound is most reactive for nuecle...

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  11. Identify the products (B) (C ) formed in the following set of reaction...

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  12. Crossed Cannizzaro reaction can be given by following combination:

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  13. The major product of the following reaction after acidification is M...

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  14. Write the product formed in the following reaction

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  15. Compound 'X' (C(4)H(8) O(2)) is a sweet smelling liquid. It gives nega...

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  16. Rank the following compounds in order of decreasing reactivity for nit...

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  17. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

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  18. Number of aldol products in the given reaction C(6)H(5) - CHO + CH(3...

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  19. Of the following which is the product formed when cyclohexanone under...

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  20. CH(2)O + CH(3)CHO underset(Delta)overset(OH^(-))(rarr) (A).(A) reacts ...

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