Home
Class 12
CHEMISTRY
In the Cannizzaro reaction given below: ...

In the Cannizzaro reaction given below:
`2Ph-CHO overset(overset(Θ)OH)rarrPh-CH_(2)OH+PhCO_(2)^(-)` the slowest step is:

A

The attack of - OH at the carbonyl group

B

The transfer of hydride to the carbonyl group.

C

The abstraction of proton from the carboxylic acid.

D

The deproatonation of Ph -`CH_(2)` OH.

Text Solution

Verified by Experts

The correct Answer is:
B

This is a fact that the determining step of the cannizarro reaction is the step of hydride transfer to the other carbonyl group.
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDES, KETONES & CARBOXYLIC ACIDS

    NARAYNA|Exercise CHECK YOUR GRASP|6 Videos
  • ALDEHYDES, KETONES & CARBOXYLIC ACIDS

    NARAYNA|Exercise EXERCISE -III|50 Videos
  • ALCOHOLS, ETHERS, PHENOL

    NARAYNA|Exercise Assertion Reaosn|10 Videos
  • AMINES & DIAZO COMPOUNDS

    NARAYNA|Exercise Subjective type Q.|13 Videos

Similar Questions

Explore conceptually related problems

In cannizzaro reaction given below 2PhCHO overset(":"overset(Theta)(O)H)toPhCH_(2)OH+Phddot(O)_(2)^(Theta) the slowest step is

In the Cannizzaro reaction , which is the slowest step ? 2PhCHOoverset(OH^(-))rarrPhCH_(2)OH+PhCOO^(-)

In the Cannizzaro reaction given below 2C_(6)H_(5)CHO overset(OH^(-))rarr C_(6)H_(5)CH_(2)OH+C_(6)H_(5)COO^(-) the slowest step is

Consider the following Cannizzaro reaction 2Ph-CHOoverset(OH^(-))rarrPh-CH_(2)OH+PhCO_(2)^(-) In the above reaction, the slowest step of the reaction is

Which of the following is not the mechanism of Cannizzaro reaction ? 2PhCHO overset(overset(Θ)(OH))rarr PhCH_(2)OH+PhCOO^(Θ)

NARAYNA-ALDEHYDES, KETONES & CARBOXYLIC ACIDS-EXERCISE -4
  1. The correct order of reactivity of PhMgBr with Ph - overset(O)overse...

    Text Solution

    |

  2. A compound (A) C(5)H(10) Cl(2) on hydrolysis gives C(5)H(10)O which re...

    Text Solution

    |

  3. Predict the product in the following reaction

    Text Solution

    |

  4. What is X ?

    Text Solution

    |

  5. Which one of the following compounds on heating with a base gives as t...

    Text Solution

    |

  6. End product of following sequence of reaction

    Text Solution

    |

  7. The formation of cyanohydrin from ketone is an example of :

    Text Solution

    |

  8. A compound (X) C(4)H(8)O Which gives a 2,4-DNP derivative and a positi...

    Text Solution

    |

  9. Which one of the following structure is not an isomer of the compound ...

    Text Solution

    |

  10. Which carbonyl group of the given compound is most reactive for nuecle...

    Text Solution

    |

  11. Identify the products (B) (C ) formed in the following set of reaction...

    Text Solution

    |

  12. Crossed Cannizzaro reaction can be given by following combination:

    Text Solution

    |

  13. The major product of the following reaction after acidification is M...

    Text Solution

    |

  14. Write the product formed in the following reaction

    Text Solution

    |

  15. Compound 'X' (C(4)H(8) O(2)) is a sweet smelling liquid. It gives nega...

    Text Solution

    |

  16. Rank the following compounds in order of decreasing reactivity for nit...

    Text Solution

    |

  17. In the Cannizzaro reaction given below: 2Ph-CHO overset(overset(Θ)OH...

    Text Solution

    |

  18. Number of aldol products in the given reaction C(6)H(5) - CHO + CH(3...

    Text Solution

    |

  19. Of the following which is the product formed when cyclohexanone under...

    Text Solution

    |

  20. CH(2)O + CH(3)CHO underset(Delta)overset(OH^(-))(rarr) (A).(A) reacts ...

    Text Solution

    |