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X overset(HI)larr "Glucose" overset(HNO3...

`X overset(HI)larr "Glucose" overset(HNO_3)to Y` what are X and Y

A

X-n -hexane , Y-Gluconic acid

B

X-Gluconic acid, Y-Saccharic acid

C

X-n-hexanol , Y-Saccharic acid

D

X-n-hexane , Y-Saccharic acid

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The correct Answer is:
To solve the question `X overset(HI)larr "Glucose" overset(HNO_3)to Y`, we need to identify the compounds X and Y based on the reactions of glucose with HI (hydriodic acid) and HNO3 (nitric acid). ### Step-by-Step Solution: 1. **Identify the structure of Glucose**: - Glucose is an aldohexose with the molecular formula C6H12O6. Its structure features an aldehyde group (-CHO) at one end and multiple hydroxyl groups (-OH) along the carbon chain. 2. **Reaction of Glucose with HNO3**: - When glucose is treated with nitric acid (HNO3), it undergoes oxidation. The aldehyde group and the hydroxyl groups are oxidized to carboxylic acid groups. - The product formed from this reaction is D-Glucaric Acid (also known as Saccharic Acid), which has the formula C6H10O8. 3. **Identify Y**: - From the oxidation of glucose with HNO3, we conclude that Y = D-Glucaric Acid (Saccharic Acid). 4. **Reaction of Glucose with HI**: - When glucose reacts with hydriodic acid (HI), it undergoes reduction. The aldehyde and hydroxyl groups are reduced to form an alkane. - The product of this reaction is n-hexane (C6H14), which is a straight-chain alkane. 5. **Identify X**: - From the reduction of glucose with HI, we conclude that X = n-Hexane. ### Final Answer: - X = n-Hexane - Y = D-Glucaric Acid (Saccharic Acid)
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NARAYNA-BIOMOLECULES-EXERCISE-4
  1. Biuret test is not given by :

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  2. The two function groups present in a typical carbohydrate are

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  3. alpha-D(+)-glucose and beta-D(+) glucose are

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  4. Number of HlO4 molecular required to complete oxidation one mole of g...

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  5. Glucose upo Ruff's degradation produces

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  6. Meso Tartaric acid

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  7. Number of moles of CH3-OH in acidic medium react with one mole of gluc...

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  8. Amino acids on treating with Ninhydrin forms

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  9. A tripeptide contains glycine, alanine and serine. How many different...

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  10. Arrange in order of increasing acid strength

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  11. An alpha-amino acid exists as, overset(+)(NH3)-underset(R)underset(|)C...

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  12. Which of the following sets of vitamins is fat soluble

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  13. The number of hydrogen bonds between guanine and cytosine, and between...

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  14. X overset(HI)larr "Glucose" overset(HNO3)to Y what are X and Y

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  15. The site of action of insulin is

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  16. The AT/GC ratio in human beings is (where A = adenin , T=thymine, G=Gu...

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  17. The base present in cytidine is

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  18. In an amino acid, the carboxyl group ionises at pK(a1) = 2.34 and ammo...

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  19. What is the pI of glycine ? The structure and pKa values are shown bel...

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  20. A sample of DNA has the ratio of (AT)/(GC) is 0.8 . If the no. of mole...

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