Home
Class 11
CHEMISTRY
Why the first ionisation enthalphy of so...

Why the first ionisation enthalphy of sodium is lower than that of magnesium while its second ionisation enthlpy is higher than that of magnesium ?

Text Solution

Verified by Experts

The "onization enthalpy of magnesium is higher than that of Na due to higher nuclear charge and slightly smaller atomic radius of Mg than Na. After the loss of first electron, Na formed has the electronic configuration of neon (2.8). The higher stability of the completely filled noble gas configuration leads to very high second ionization enthalpy for sodium. On the other hand, `Mg^+` formed after losing first electron still has one more electron in its outermost(s) orbital. As a result, the second ionization enthalpy of magnesium is much smaller than that of sodium
Promotional Banner

Topper's Solved these Questions

  • PERIODIC CLASSIFICATION OF ELEMENTS

    FULL MARKS|Exercise In-Text Question-Evaluate Yourself|7 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS

    FULL MARKS|Exercise Additional Questions(M.C.Q)|38 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS

    FULL MARKS|Exercise Textual Evaluation Solved(Choose the correct answer)|10 Videos
  • HYDROGEN

    FULL MARKS|Exercise Additional Questions Solved 5-Mark Questions|10 Videos
  • PHYSICAL AND CHEMICAL EQUILIBRIUM

    FULL MARKS|Exercise ADDITIONAL QUESTIONS SOLVED (NUMERICAL PROBLEMS)|3 Videos

Similar Questions

Explore conceptually related problems

Give reasons: (i) IE_(1) of sodium is lower than that of magnesium whereas IE_(2) of sodium is higher than that of magnesium. (ii) Noble gases have positive value of electron gain enthalpy.

The ionisation constant of phenol is higher than that of ethanol because

Why the first ionization energy of alkaline earth metals higher than that of Ist group.

FULL MARKS-PERIODIC CLASSIFICATION OF ELEMENTS -Textual Evaluation Solved( II brief question)
  1. Magnesium loses electrons successively to form Mg^(+),Mg^(2+)andMg^(3+...

    Text Solution

    |

  2. Define electronegativity .

    Text Solution

    |

  3. How would you explain the fact that the second ionisation potential is...

    Text Solution

    |

  4. Energy of an electron in the ground state of the hydrogen atom is-2.18...

    Text Solution

    |

  5. The electronic configuration of atom is one of the important factor wh...

    Text Solution

    |

  6. In what period and group will an element with Z-118 will be present?

    Text Solution

    |

  7. Justify that the fifth period of the periodic table should have 18 el...

    Text Solution

    |

  8. Elements a,b,c and d have the following electronic configurations: ...

    Text Solution

    |

  9. Give the general electronic configuration of lanthanides and actides?

    Text Solution

    |

  10. Why halogens act as oxidising agents?

    Text Solution

    |

  11. Mention any two anomalous properties of second period elements.

    Text Solution

    |

  12. Explain the pauling method for the determination os ionic radius.

    Text Solution

    |

  13. Explain the periodic trend of ionisation potential.

    Text Solution

    |

  14. Explain the diagonal relationship

    Text Solution

    |

  15. Why the first ionisation enthalphy of sodium is lower than that of mag...

    Text Solution

    |

  16. Calculate the ionic radii of K^(+) and Cl^(-) ions in KCl crystal. T...

    Text Solution

    |

  17. Explain the following, give appropriate reasons. (i) Ionization po...

    Text Solution

    |

  18. What is screening effect ?

    Text Solution

    |

  19. Briefly give the basis for pauling's scale of electronegativity.

    Text Solution

    |

  20. State the trends in the variation of electronegativity in group and pe...

    Text Solution

    |