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Li(2)CO(3) decomposes readily whereas ot...

`Li_(2)CO_(3)` decomposes readily whereas other carbonates are not. Why?

Text Solution

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The carbonates `(M_(2)CO_(3))` of alkali metals are remarkably more stable upto 1270K above which they first melt and then decompose to form their oxides, whereas `Li_(2)CO_(3)` is less stable and decomposes readily
`Li_(2)CO_(3) + /_\ to Li_(2)O + CO_(2)uarr`
This is due to the large size difference between `Li^(+)` and `Co_(3)^(2-)` which makes the crystal lattice unstable
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