Home
Class 11
CHEMISTRY
Calculate the enthalpy of hydrogenation ...

Calculate the enthalpy of hydrogenation of ethylene from the following data. Bond energies of C-H , C-C , C=C and H-H are 414,347,618 and 435 kJ `mol^(-1)` .

Text Solution

Verified by Experts

Given : `E_(C-H)=414 "kJ mol"^(-1)`
`E_(C-C)=347 "kJ mol"^(-1)`
`E_(C=C)=618 "kJ mol"^(-1)`
`E_(H-H)=435 "kJ mol"^(-1)`

`DeltaH_r=sum "(Bond energy)"_r -sum "(Bond energy)"_p`
`DeltaH_r=(E_(C=C)+4E_(C-H)+E_(H-H))-(E_(C-C) +6E_(C-H))`
`DeltaH_r` = (618 + ( 4 x 414 ) + 435 ) -(347 +(6 x 414))
`DeltaH_r`=2709-2831
`DeltaH_r=-122 "kJ mol"^(-1)`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    FULL MARKS|Exercise In-Text Questions -Evaluate Yourself|8 Videos
  • THERMODYNAMICS

    FULL MARKS|Exercise Additional Questions Solved (I)|39 Videos
  • THERMODYNAMICS

    FULL MARKS|Exercise Textual Question Solved (MCQs)|25 Videos
  • SOLVED PAPER 13 (UNSOLVED)

    FULL MARKS|Exercise PART-II|9 Videos

Similar Questions

Explore conceptually related problems

Calculate the ratio (C_p / C_v) of oxygen from the following data . Speed of sound in oxygen (= 32g mol^(-1)) and the gas constant (R = 8.3 J K ^(-1) mol^(-1)) .

Calculate the lattice energy of formation of NaCl from the following data : Na_((s)) +1//2Cl_(2(g)) to NaCl_((s)) Delta H_(f) -411.3 KJ.mol^(-1) Heat of sublimation of Na_((s)) = 108 . 7 kJ mol ^(-1) Ionisation energy of Na_((g)) = 49.5.0 kJ mol^(-1) Dissociation energy of Cl_(2(g)) = 244 kJ mol^(-1) Electron affinity of Cl_((g)) = - 349 . 0 kJ mol^(-1)

Calculate the respiratory quotient for the following equation. C_6H_12O_6 to 2CO_2 + 2C_2H_5OH + "Energy"

Calculate the standard enthalpy of formation of CH_3OH_((l)) from the following data : (i) CH_3OH_((l)) +3//2 O_(2(g)) to CO_(2(g)) + 2H_2O_((l)) , Delta_r H^(Ө)=-726 "kJ mol"^(-1) (ii) C_((s)) + O_(2(g)) to CO_(2(g)) , Delta_c H^(Ө)=-393 "kJ mol"^(-1) (iii) H_(2(g)) +1//2O_(2(g)) to H_2O_((l)) , Delta_f H^(Ө)=-286 "kJ mol"^(-1)

FULL MARKS-THERMODYNAMICS -Textual Question Solved
  1. Define Gibb's free energy .

    Text Solution

    |

  2. Calculate the work done when 2 moles of an ideal gas expands reversibl...

    Text Solution

    |

  3. In a constant volume calorimeter, 3.5 g of a gas with molecular weight...

    Text Solution

    |

  4. Calculate the entropy change in the system and surroundings, and the t...

    Text Solution

    |

  5. 1 mole of an ideal gas, maintained at 4.1 atm and at a certain tempera...

    Text Solution

    |

  6. 30.4 kJ is required to melt one mole of sodium chloride. The entropy c...

    Text Solution

    |

  7. Calculate the standard heat of formation of propane, if its heat of co...

    Text Solution

    |

  8. You are given normal boiling points and standard enthalpies of vaporiz...

    Text Solution

    |

  9. DeltaH and DeltaS for the reaction Ag(2)O((s))rarr2Ag((s))+1/2O(2((g...

    Text Solution

    |

  10. What is the equilibrium constant K(eq) for the following reaction at 4...

    Text Solution

    |

  11. Cyanamide (NH2CN) is completely burnt in excess oxygen in a bomb calor...

    Text Solution

    |

  12. Calculate the enthalpy of hydrogenation of ethylene from the following...

    Text Solution

    |

  13. Calculate the lattice energy of CaCl2 from the given data. Ca((s)) +...

    Text Solution

    |

  14. Calculate the enthalpy change for the reaction Fe2O3 +3CO to 2Fe +3CO2...

    Text Solution

    |

  15. When 1-pentyne (A) is treated with 4N alcoholic KOH at 175^@C, it is c...

    Text Solution

    |

  16. At 33K , N(2)O(4) is fifty percent dissociated Calculate the standard ...

    Text Solution

    |

  17. The standard enthalpies of formation of SO2 and SO3 are -297 "kJ mol"...

    Text Solution

    |

  18. For the reaction at 298 K : 2A +B to C DeltaH="400 KJ mol"^(-1) , De...

    Text Solution

    |

  19. Find out the value of equilibrium constant for the following reaction ...

    Text Solution

    |

  20. A gas mixture of 3.67 lit of ethylene and methane on complete combusti...

    Text Solution

    |