Which of the following shows negative deviation from Raoult's law ?

Explanation

The variation of vapour pressure of pure benzene and toluene with its mole fraction is given in the graph.
(i) The vapour pressure of pure toluene and pure benzene are `22.3 and 74.7` mm Hg respectively.
(ii) The graph shows the partial vapour pressure of pure components increase linearly with the increase of the mole fraction of the respective components. The total pressure at any composition of the solute and solvent is given by the straight line.
`P _("solution") =P_("toluene") ^(0) + x_("benzene") (P_("benzene")^(0) -P_("toluenc")^(0))`