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How would you campare Raoult's law and H...

How would you campare Raoult's law and Henry's law.

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(i) According to Raoult.s law, for a solution containing a non volatile solute,
`P _("solute")=P _("solute"^(0) x _("solute")`
(ii) According to Henry.s law, `P_("solute")=K_(H),x_("solute")` in solution
(iii) The difference betwwn the abouve two laws is the proportionality constant `P^(@)` (Raoult.s law) and `K_(H)` (Henry.s law).
(iv) Henry.s law is applicable to solution containing gaseous solute in liquid solvent, while Raoult.s law is applicable to non volatile solid solute in the liquid solvent.
(v) If the solute is non volatilethen the Henry.s law constant will become equal to the vapour pressure of puire solvent `P^(@),` thus Raoult.s law becomes a special case of Henry.s law.
(v) For very dilute solutions, the solvent obeys Raoult.s law and the solute obeys Henry.s law.
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FULL MARKS-SOLUTIONS -ADDITIONAL QUESTIONS SOLVED - 3 MARKS QUESTIONS
  1. Which of the following shows negative deviation from Raoult's law ?

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  2. Derive the relationship between the elevation of boiling point and mol...

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  3. How would you campare Raoult's law and Henry's law.

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  4. What are the necessary conditions for an ideal solution? Give two exam...

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  5. Which of the following shows positive deviation from Raoult's law ?

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  6. Which of the following shows negative deviation from Raoult's law ?

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  7. Explain why boiling point of solution is greater than that of pure sol...

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  8. Define relative lowering of vapour pressure.

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  9. Explain why boiling point of solution is greater than that of pure sol...

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  10. Graphically prove that T(b) is greater than T(b) ^(@).

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  11. Derive the relationship between the elevation of boiling point and mol...

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  12. Write short note an freezing point depression in freezing point and cr...

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  13. Define (i) cryoscopic constant (ii) ebullioscopic constant

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  14. Discuss the significances of osmotic-pressure over other colligative p...

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  15. What is haemolysis? Why intravenous fluid are isotonic to blood ?

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  16. What is reverse osmosis?

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  17. Explain about the application of reverse osmosis in water purification...

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  18. Acetic acid is found to have molar mass as 120 g mol ^(-1). Prove it.

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  19. Prove that the depression in freezing point is a colligative property.

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  20. The estimated van't Hoff factor for acetic acid solution in benzene is...

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