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Draw the MO diagram for acetylide ion C(...

Draw the MO diagram for acetylide ion `C_(2)^(2-)` and calculate its bond order.

Text Solution

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Acetylide ion, `C_(2)^(2-)` in acetylene: `underset(1s^(2)" "2s^(2)" "2p^(4))(C)rarrunderset(1s^(2)" "2s^(2)" "2p^(2))(C^(2-)+2e)`
Electronic configuration of `C_(2)^(2-)` ion is : `sigma 1s^(2) sigma **1s^(2)sigma1s^(2) pi2p_(x)^(2)pi2p_(y)^(2)`

Bond order `= (N_(b)-N_(a))/(2)=(8-4)/(2)=2`
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