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What are the main postulates of Valence ...

What are the main postulates of Valence Shell Electron Pair Repulsion (VSEPR) theory?

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(i) The shape of a molecule depends upon the no. of electron pairs around the centra atom.
(ii) There is a repulsive force between the electron pairs, which tend to repel one another.
(iii) The electron pairs in space tend to occupy such positions that they are at maximum distance, so that the repulsive force will be minimum.
(iv) A multiple bond is treated as ifit 1s a single bond and the remaining electron pairs which onstitute the bond may be regarded as single super pair.
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Knowledge Check

  • Assertion(A): The bond angle (C-O-H) in methanol is reduced to 108.9^@ from the regular tetra hedral bond angle of 109.5^@ . Reason (R): In methanol, two one pairs of electrons are present in oxygen atom and due to lone pair - lone pair repulsion, the bond angle is reduced.

    A
    Both A and R are correct and R is the correct explanation of A.
    B
    Both A and R are correct but R is not the correct explanation of A
    C
    A is correct but R is wrong
    D
    A is wrong but R is correct
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