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Assertion : In biospy test for cancer, ...

Assertion : In biospy test for cancer, piece of the suspected tissue cut into thin sections is stained and examined under X -ray by a pathologist.
Reason : Use of X-ray is able to generate a 3-D image of the section of affected tissue.

A

If both Assertion & Reason as true & the Reason is a correct explanation of the assertion.

B

If both Assertion & Reason are True but Reason is not a correct explanation of the Assertion.

C

If Assertion is True but the Reason is False.

D

If both Assertion & Reason are false.

Text Solution

Verified by Experts

The correct Answer is:
D
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Read the passage given below and answer the following questions: Reduction of carboxylic acids and their derivatives plays an important role in organic synthesis, in both laboratory and industrial processes. Traditionally, the reduction is performed using stochiometric amounts of hydride reagents, generating stochiometric amounts of waste. A much more attractive, atom-economical approach is a catalytic reaction using H_2 , however, hydrogenation of carboxylic acid derivatives under mild conditions is a very challenging task, with amides presenting the highest challenge among all classes of carbonyl compounds. Very few examples of the important hydrogenation of amides to amines, in which the C-O bond is cleaved with the liberation of water (Scheme 1), were reported. C-O cleavage of amides can also be affected with silanes as reducing agents. We have now prepared the new, dearomatized, bipyridine-based pincer complex 3, catalyst 3(Here refered as Cat. 3). Remarkably, it efficiently catalyzes the selective hydrogenation of amides to form amines and alcohols (eq 1). The reaction proceeds under mild pressure and neutral conditions, with no additives being required. Since the reaction proceeds well under anhydrous conditions, hydrolytic cleavage of the amide is not involved in this process. (Balaraman, E., Gnanaprakasam, B., Shimon, L. J., & Milstein, D. (2010). Direct hydrogenation of amides to alcohols and amines under mild conditions. Journal of the American Chemical Society, 132(47), 16756-16758.) In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage. Assertion: N-methyl ethanamide on reaction with catalyst 3 will yield ethanol and methanamine. Reason: Use of Catalyst 3 brings about cleavage of C-N bond of amides

Read the passage given below and answer the following questions: Reduction of carboxylic acids and their derivatives plays an important role in organic synthesis, in both laboratory and industrial processes. Traditionally, the reduction is performed using stochiometric amounts of hydride reagents, generating stochiometric amounts of waste. A much more attractive, atom-economical approach is a catalytic reaction using H_2 , however, hydrogenation of carboxylic acid derivatives under mild conditions is a very challenging task, with amides presenting the highest challenge among all classes of carbonyl compounds. Very few examples of the important hydrogenation of amides to amines, in which the C-O bond is cleaved with the liberation of water (Scheme 1), were reported. C-O cleavage of amides can also be affected with silanes as reducing agents. We have now prepared the new, dearomatized, bipyridine-based pincer complex 3, catalyst 3(Here refered as Cat. 3). Remarkably, it efficiently catalyzes the selective hydrogenation of amides to form amines and alcohols (eq 1). The reaction proceeds under mild pressure and neutral conditions, with no additives being required. Since the reaction proceeds well under anhydrous conditions, hydrolytic cleavage of the amide is not involved in this process. (Balaraman, E., Gnanaprakasam, B., Shimon, L. J., & Milstein, D. (2010). Direct hydrogenation of amides to alcohols and amines under mild conditions. Journal of the American Chemical Society, 132(47), 16756-16758.) In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage. Assertion: Use of hydride catalyst or hydrogen brings about cleavage of C-O bond in amides. Reason: Hydride catalyst or hydrogen cause to reduction of amides.

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