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The rate of formation of a dimer in a se...

The rate of formation of a dimer in a second order reaction is `7.5xx10^(-3)"mol L"^(-1)s^(-1)` at `0.05"mol L"^(-1)` monomer concentration. Calculate the rate constant.

Text Solution

Verified by Experts

Let us consider the dimerisation of a monomer M
`2Mrarr(M)_(2)`
`"Rate "=k[M]^(n)`
`"Given that n = 2 and [M]"="0.05 mol L"^(-1)`
`"Rate "=7.5xx10^(-3)" mol L"^(-1)s^(-1)`
`k=("Rate")/([M]^(n))rArr k=(7.5xx10^(-3))/((0.05)^(2))="3 mol"^(-1)L s"^(-1)`
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