Home
Class 12
CHEMISTRY
The extraction of Au by leaching with Na...

The extraction of Au by leaching with NaCN involves both oxidation and reduction.Justify by giving equation.

Text Solution

Verified by Experts

`4Au(s)+8CN^(-)(aq)+2H_(2)O(aq)+O_(2)(g)to4[Au(CN)_(2)]^(-)(aq)+4OH^(-)(aq)`
`2[Au(CN)_(2)]^(-)(aq)+Zn(s)to2Au(s)+[Zn(CN)_(4)]^(-2)(aq)`
In the first reaction Au changes into `Au^(+)`,i.e its oxidation takes place.In the second reaction:
`Au^(+)toAu^(@)` (i.e) reduction takes place.
Promotional Banner

Topper's Solved these Questions

  • METALLURGY

    FULL MARKS|Exercise Additional questions - ( 5 MARK QUESTIONS )-Answer the following questions.|8 Videos
  • METALLURGY

    FULL MARKS|Exercise Additional questions - ( 2 MARK QUESTIONS )-Answer the following:|30 Videos
  • IONIC EQUILIBRIUM

    FULL MARKS|Exercise ADDITIONAL QUESTIONS (5 MARK QUESTION)|15 Videos
  • ORGANIC NITROGEN COMPOUNDS

    FULL MARKS|Exercise ADDITIONAL QUESTIONS (5-MARK QUESTIONS)|14 Videos

Similar Questions

Explore conceptually related problems

Write the equation for the extraction of silver by leaching with sodium cyanide and show that the leaching proces is a redox reaction.

Identify the correct statements with reference to the given reaction P_4 +3OH^(-)+3H_(2)Oto PH_(3)+3H_(2)PO_(2)^(-) (i) Phosphorous is undergoing reduction only (ii) Phorphorous is undergoing oxidation only (iii) Phosphorous is undergoing both oxidation and reduction . (iv) Hydrogen is undergoing neither oxidation nor reduction .

An element A occupies group number 15 and period number 3, reacts with chlorine to give compound B. The compounds B on hydrolysis gives a dibasic acid C. The compound C on heating undergoes auto oxidation and reduction to give a tribasic acid D. Identify the elements A, compounds B, C and D. Write the reactions.

Extraction of gold and silver involves leaching with cyanide ion. Silver is later recovered by