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The percentage of pyridine (C5H5N) that ...

The percentage of pyridine `(C_5H_5N)` that forms pyridinium ion `(C_5H_5NH)` in a 0.10 M aqueous pyridine solution `(K_b` for `C_5H_5N=1.7 times 10^-9`) is………..

A

`0.006%`

B

`0.013%`

C

`0.77%`

D

`1.6%`

Text Solution

Verified by Experts

`C_5H_5N+H-OH leftrightarrowC_5H_5NH+OH^(-)`
`(a^2C)/(1-a)=K_b`
`a^2C approxK_b`
`a=sqrt((K_b)/C)sqrt((1.7 times 10^-9)/(0.1))=sqrt1.7 times 10^-4`
Percentage of dissociation
`sqrt1.7 times 10^-4 times 100=1.3 times 10^-2=0.013%`
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