Home
Class 12
CHEMISTRY
50 ml of 0.05 M HNO3 is added to 50 ml o...

50 ml of 0.05 M `HNO_3` is added to 50 ml of 0.025 M KOH. Calculate the pH of the resultant solution.

Text Solution

Verified by Experts

Number of moles of `HNO_3=0.05 times 50 times 10^-3=2.5 times 10^-3`
Number of moles of KOH=`0.025 times 50 times 10^-3=1.25 times 10^-3`
Number of moles of `HNO_3` after mixing =`2.5 times 10^-3-1.5 times 10^-3=1.25 times 10^-3`
`therefore " Concentration of " HNO_3= ("Number of moles of" HNO_3)/( "Volume in litre")`
After mixing total volume=`1.25 times 10^-2 moles L^-1`
`therefore[H^+]=(1.25 times10^-3 mol es)/(100 times10^-3L)=1.25 times10^-2mol es L^-1`
`pH=-log[H^+]`
`pH=-log(1.25 times10^-2)=2-0.0969`
`=1.9031`
Promotional Banner

Topper's Solved these Questions

  • IONIC EQUILIBRIUM

    FULL MARKS|Exercise EVALUATE YOURSELF|10 Videos
  • IONIC EQUILIBRIUM

    FULL MARKS|Exercise ADDITIONAL QUESTIONS (CHOOSE THE BEST ANSWER)|51 Videos
  • IONIC EQUILIBRIUM

    FULL MARKS|Exercise TEXTBOOK EVALUATION (CHOOSE THE CORRECT ANSWER)|25 Videos
  • HYDROXY COMPOUNDS AND ETHERS

    FULL MARKS|Exercise ADDITIONAL QUESTIONS (Answer the following)|115 Videos
  • METALLURGY

    FULL MARKS|Exercise Additional questions - ( 5 MARK QUESTIONS )-Answer the following questions.|8 Videos

Similar Questions

Explore conceptually related problems

Calculate the pH of "0.001 M HCl" solution

FULL MARKS-IONIC EQUILIBRIUM-TEXTBOOK EVALUATION (ANSWER THE FOLLOWING QUESTION:)
  1. Calculate the pH of 0.04 M HNO3 solution.

    Text Solution

    |

  2. Define solubility product.

    Text Solution

    |

  3. Define ionic product of water. Given its value at room temperature.

    Text Solution

    |

  4. Explain common ion effect with an example.

    Text Solution

    |

  5. Derive an expression for Ostwaid's dilution law.

    Text Solution

    |

  6. Define pH.

    Text Solution

    |

  7. Calculate the pH of 1.5 times 10^-3 M solution of Ba(OH)2.

    Text Solution

    |

  8. 50 ml of 0.05 M HNO3 is added to 50 ml of 0.025 M KOH. Calculate the p...

    Text Solution

    |

  9. The Ka value for HCN is 10^-9. What is the pH of 0.4 M HCN solution?

    Text Solution

    |

  10. Calculate the extent of hydrolysis and the pH of 0.1 M ammonium acetat...

    Text Solution

    |

  11. Derive an expression for the hydrolysis constant and degree of hydroly...

    Text Solution

    |

  12. Solubility produce of Ag2CrO4 is 1 times 10^-12. What is the solubilit...

    Text Solution

    |

  13. Write the expression for the solubility produce of Ca3(PO4)2

    Text Solution

    |

  14. A saturated solution, prepared by dissolving CaF2(s) in water, has [Ca...

    Text Solution

    |

  15. K(sp) of AgCl is 1.8 times 10^-10. Calculate molar solubility in 1M A...

    Text Solution

    |

  16. A particular saturated solution of silver chromate AgCrO4 has [Ag^+]=5...

    Text Solution

    |

  17. Write the expression for the solubility produce of Hg2Cl2.

    Text Solution

    |

  18. K(sp) of Ag2CrO4 is 1.1 times 10^-12. What is solubility of Ag2CrO4 in...

    Text Solution

    |

  19. Will a precipitate be formed when 0.150 L of 0.1 M Pb(NO3)2 and 0.100 ...

    Text Solution

    |

  20. K(sp) of Al(OH)3 is 1 times 10^-15 At what pH does 1.0 times 10^-3 M ...

    Text Solution

    |