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Which one of the following reactions pro...

Which one of the following reactions proceeds through free radical chain mechanism?

A

Hydrolysis of tert-butyl chloride with aqueous KOH

B

Photochemical chlorination of methane

C

Addition of HBr to ethene

D

Addition of `NaHSO_(3)` on acetone

Text Solution

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The correct Answer is:
B
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OP TANDON-BASIC PRINCIPLES OF ORGANIC COMPOUNDS (MECHANISM OF ORGANIC REACTIONS)-OBJECTIVE QUESTIONS (Level-A)
  1. The peroxide effect in anti-Markownikoff's additon involves:

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  2. The decreasing order of strength of the bases, OH^(-), NH(2)^(-), H-C-...

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  3. Which one of the following reactions proceeds through free radical cha...

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  4. Which is the decreasing oreder of acidity in the following compounds? ...

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  5. Carbocation is a reaction intermediate in which of the following react...

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  6. The compound that does not undergo hydrolysis by S(N^(1)) mechanism is...

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  7. Which one is a nucleophilic substitution reaction among the following ...

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  8. Hypercojnugation is not possible in :

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  9. Reimer-Tiemann reaction of phenol with cholorform and aqueous alkali t...

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  10. The reaction intermediate carbenes are produced from"

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  11. In the following group : -OAc(I),-OMe(II),-OSO(2)(III),-OSO(2)CF(3)(...

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  12. ":CCl"(2) is :

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  13. In additon reactions of alkenes, the Markownikoff's rule follow:

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  14. Addition of HBr to propene in presence of peroxide (antiMarkownikoff's...

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  15. A nucleophile must have :

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  16. In a Friedel-Crafts reaction, the electrophile is:

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  17. Arrange the following carbanions in decreasing orde of stability: HC...

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  18. Arrange the following carbocations in order of increasing stability : ...

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  19. Which one of the following behaves both as a nucleophile and an electr...

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  20. Consider the following bromides: The correct order of S(N^(1)) re...

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