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The arrangement of following compounds ...

The arrangement of following compounds :
i. bromomethane ii.bromoform
iii. Chloromethane iv. Dibromomethane
In the increasing order of their boiling point is

A

`iv lt iii lt i lt ii`

B

`i lt ii lt iii lt iv`

C

`iii lt i lt iv lt ii`

D

`ii lt iii lt i lt iv `

Text Solution

Verified by Experts

The correct Answer is:
C

The intermolecular forces of attraction become stronger with the increase in size of the molecules . Hence the order of boiling points will be :
`Cch_(3)Cl lt CH_(3)Br lt CH_(2)Br_(2)lt CHBr_(3)`
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