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In presence of HCl, H2S results the prec...

In presence of HCl, `H_2S` results the precipitatiion of Group-2 elements but not Group -4 elements during qualitative analysis. If is due to

A

higher concentration of `H^(+)`

B

lower concentration of `H^(+)`

C

higher concentration of `S^(2-)`

D

lower concentration of `S^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B

Dissociation of `H_(2)S` is suppressed in presence of HCl due to common ion effect . This decreases the `S^(2-)` ion concentration and hence , only group II radicals having low solubility product are precipitated .
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