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Justify the placement of O, S, Se, Te an...

Justify the placement of O, S, Se, Te and Po in the same group of the periodic table in terms of electronic configuration, oxidation states and hydride formation.

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Numerous forms of the periodic table have been devised from time to time. A modern version which is most convenient and widely used is the long or extended from of periodic table. The aufbau principle and the electronic configuration of atoms provide a theoretical foundation for the periodic classification. The horizontal rows are called periods. There are altogether seven periods. The first period consists of 2 elements. The subsequent periods consists of 8, 8,18, 18 and 32 elements respectively. The seventh period is incomplete and like the sixth period would have maximum of 32 elements. Elements having similar outer electronic configurations in their atoms are grouped in vertical columns. These are referred to as groups or families. According to the recommendations of IUPAC, the groups are numbered 1 to 18 replacing the older notation of groups 0, IA, IIA, ....VIIA, VIII, IB.....VIIB. Each successive period in the periodic table is associated with the filling up next higher principal energy level following aufbau sequence. The number of elements in each period is twice the number of atomic orbitals available in the energy level that is being filled. All the elements are classified into four blocks, i.e., s-block, p-block, d-block, and f-block depending on the type of atomic orbitals that are being filled with electrons. What is the position of the element in the periodic table satisfying the electronic configuration (n-1)d^1 ns^2 for n=4 ?

Numerous forms of the periodic table have been devised from time to time. A modern version which is most convenient and widely used is the long or extended from of periodic table. The aufbau principle and the electronic configuration of atoms provide a theoretical foundation for the periodic classification. The horizontal rows are called periods. There are altogether seven periods. The first period consists of 2 elements. The subsequent periods consists of 8, 8,18, 18 and 32 elements respectively. The seventh period is incomplete and like the sixth period would have maximum of 32 elements. Elements having similar outer electronic configurations in their atoms are grouped in vertical columns. These are referred to as groups or families. According to the recommendations of IUPAC, the groups are numbered 1 to 18 replacing the older notation of groups 0, IA, IIA, ....VIIA, VIII, IB.....VIIB. Each successive period in the periodic table is associated with the filling up next higher principal energy level following aufbau sequence. The number of elements in each period is twice the number of atomic orbitals available in the energy level that is being filled. All the elements are classified into four blocks, i.e., s-block, p-block, d-block, and f-block depending on the type of atomic orbitals that are being filled with electrons. Elements A, B, C, D and E have the following electronic configuration: (A) 1s^2, 2s^2 2p^1 (B) 1s^2, 2s^2 2p^6 , 3s^2 3p^1 (C ) 1s^2, 2s^2 2p^6 , 3s^2 3p^3 (D) 1s^2 , 2s^2 2p^6 , 3s^2 3p^5 (E) 1s^2 , 2s^2 2p^6 , 3s^2 3p^6 Which among these will belong to same group in the periodic table ?

NCERT TELUGU-THE P-BLOCK ELEMENTS -Exercises
  1. Give the disproportionation reaction of H(3)PO(3).

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  2. Can PCl(5) act as an oxidising as well as a reducing agent? Justify.

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  3. Justify the placement of O, S, Se, Te and Po in the same group of the ...

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  4. Why is dioxygen a gas but sulphur a solid ?

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  5. Knowing the electron gain enthalpy values for O to O^(-) and O to O^(2...

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  6. Which aerosols deplete ozone?

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  7. Describe the manufacture of H(2)SO(4) by contact process.

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  8. How is SO(2) an air pollutant?

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  9. Why are halogens strong oxidising agents?

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  10. Explain why fluorine forms only one oxoacid, HOF.

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  11. Explain why inspite of nearly the same electronegativity, oxygen forms...

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  12. Write two uses of ClO(2).

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  13. Why are halogens coloured ?

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  14. Write the reactions of F(2) and Cl(2) with water.

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  15. How can you prepare Cl(2) from HCl and HCl from Cl(2) ? Write the reac...

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  16. What inspired Bartlett for carrying out reaction between Xe and PtF(6)...

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  17. What are the oxidation states of phosphorus in the following ? "PCl"...

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  18. Write balanced equations for the folliowing. NaCl is heated with "C...

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  19. How are Xenon fluorides XeF(2),XeF(4) and XeF(6) obtained ?

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  20. With which neutral molecule, ClO^(-) is isoelectronic ? Is that molecu...

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