Derive the structure of (i) 2-Chlorohexane, (ii) Pent-4-en-2-ol, (iii) 3- Nitrocyclohexene, (iv) Cyclohex-2-en-1-ol, (v) 6-Hydroxy- heptanal.

Explanation

(i) ‘hexane’ indicates the presence of 6 carbon atoms in the chain. The functional group chloro is present at carbon 2. Hence, the structure of the compound is `CH_(3)CH_(2)CH_(2)CH_(2)CH(Cl)CH_(3)`.
(ii) ‘pent’ indicates that parent hydrocarbon contains 5 carbon atoms in the chain. ‘en’ and ‘ol’ correspond to the functional groups C=C and -OH at carbon atoms 4 and 2 respectively. Thus, the structure is
`CH_(2)=CHCH_(2)CH(OH)CH_(3)`.
(iii) Six membered ring containing a carbon-carbon double bond is implied by cyclohexene, which is numbered as shown in (I). The prefix 3-nitro means that a nitro group is present on C-3. Thus, complete structural formula of the compound is (II). Double bond is suffixed functional group whereas `NO_(2)` is prefixed functional group therefore double bond gets preference over `–NO_(2)` group:

(iv) ‘1-ol’ means that a -OH group is present at C-1. OH is suffixed functional group and gets preference over C=C bond. Thus the structure is as shown in (II):

(v) ‘heptanal’ indicates the compound to be an aldehyde containing 7 carbon atoms in the parent chain. The ‘6-hydroxy’ indicates that -OH group is present at carbon 6. Thus, the structural formula of the compound is: `CH_(3)CH(OH)CH_(2)CH_(2)CH_(2)CH_(2)CHO`. Carbon atom of `–CHO` group is included while numbering the carbon chain.