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Giving justification, categorise the fol...

Giving justification, categorise the following moelcules/ions as nucleophile or electrophile:
`HS^(-),BF_(3),C_(2)H_(5)O^(-),(CH_(3))_(3)N`:
`Coverset(+)(l),CH_(3)-overset(+)(C)=O,H_(2)Nbar:,overset(+)(N)O_(2)`

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Nucleophiles: `HS^(-),C_(2)H_(5)O^(-),(CH_(3))_(3)N:,H_(2)N:^(-)`
These species have unshared pair of electrons, which can be donated and shared with an electrophile.
Electrophiles : `BF_(3),Coverset(+)l,CH_(3)-overset(+)(C)=O,overset(+)(N)O_(2)`.
Reactive sites have only six valence electrons, can accept electron pair from a nucleophile.
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Categorise the following species as nucleophile or electrophile : RNH^(-) , RSH, H_(3)O^(+), AlCl_(3), X^(-), R_(3)C^(+)

Identify the reagents shown in bold in the following equations as nucleophiles or electrophiles: (a) CH_(3)COOH+HO^(-)rarrCH_(3)COO^(-)+H_(2)O (b) CH_(3)COCH_(3)+overset(-)(C )Nrarr(CH_(3))_(2)C(CN)(OH) (c ) C_(6)H_(5)+CH_(3)overset(+)(C )OrarrC_(6)H_(5)COCH_(3)

Which of the following carbocation is most stable ? (a) (CH_(3))_(3)C.overset(+)(C )H_(2) (b) (CH_(3))_(3)overset(+)(C ) (c ) CH_(3)CH_(2)overset(+)(C )H_(2) (d) CH_(3)overset(+)(C )HCH_(2)CH_(3)

Separate nucleophiles and electrophiles from: H_(3)O^(+), RCOO^(-), BF_(3) R-O-R, NH_(3), R_(3)C^(+) and ZnCI_(2) .

The IUPAC name of CH_(3)-overset(O)overset(||)C-O-CH_(2)-CH=CHCH_3

IUPAC name of CH_(3)-overset(C_(2)H_(5))overset("| ")underset(C_(2)H_(5))underset("| ")("C ")-CH_(3)

IUPAC name of CH_(2)=underset(CH_(3))underset("| ")("C ")-CH_(2)-overset(O)overset("||")("C")-O Et

IUPAC name of the compound is H_(3)C-CH_(2)-overset(CHCl_(2))overset("| ")("CH ")-overset(C Cl_(3))overset("| ")("CH")-CH_(2)CH_(3)

CH_(3)-CH_(2)-CH=CH-CH_(3)+O_(3)underset("Zn")overset(H_(2)O)rarr

NCERT TELUGU-ORGANIC CHEMISTRY - SOME BASIC PRINCIPLES AND TECHNIQUES -EXERCISES
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  2. What are hybridisation states of each carbon atom in the following com...

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  3. Indicate the σ and π bonds in the following molecules : C(6)H(6),C(6...

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  4. Write bond line formulas for : Isopropyl alcohol, 2,3-Dimethyl butanal...

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  5. Give the IUPAC names of the following compounds : (a) (b) Cl(2)CHCH...

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  6. Which of the following represents the correct IUPAC name for the compo...

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  7. Draw formulas for the first five members of each homologous series beg...

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  8. Give condensed and bond line structural formulas and identify the func...

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  9. Identify the functional groups in the following compounds

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  10. Which of the two: O(2)NCH(2)CH(2)O^(–) or CH(3)CH(2)O^(–) is expected ...

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  11. Explain why alkyl groups act as electron donors when attached to a π s...

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  12. Draw the resonance structures for the following compounds. Show the el...

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  13. What are electrophiles and nucleophiles ? Explain with examples.

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  14. Identify the reagents shown in bold in the following equations as nucl...

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  15. Classify the following reactions in one of the reaction type studied i...

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  16. For the following bond cleavages, use curved-arrows to show the electr...

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  17. Explain the terms Inductive and Electromeric effects. Which electron d...

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  18. Give a brief description of the principles of the following techniques...

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  19. Describe the method, which can be used to separate two compounds with ...

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  20. What is the difference between distillation, distillation under reduce...

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  21. Discuss Lassigne's test.

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