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Assign reason for each of the following ...

Assign reason for each of the following :
(i) Transition elements exhibit paramagnetic behaviour .
(ii) `Co^(2+)` is easily oxidised in the presence of a strong ligand

Text Solution

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(i) The low ionisation potentials mean that the elements show variable valency states that compounds of the transtion element can be paramnetic .This suggests that the electrons which enter the d orbitals are being used
(ii) In presence of strong ligand the pairing of d electrons takes place and the valence shell electorinic configuration of `Co^(2)` and `CO^(3+)` ions can be represented as follow

Since the `l_(g)` level is at higher energy than `t_(2g)` level `Co^(2+)` ion is less stable than `Co^(3+)` ion morevoer the electrons in `l_(g)` level lower crystal field stablistion energy of `Co^(2+)` ion So `Co^(2+)` is easily oxidized to `CO^(3+)` in presence of a strong ligand
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