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The radius of Na(+) is 95 pm and that of...

The radius of `Na(+)` is 95 pm and that of `CI^(-)`ions is 181 pm. Predict whethr the coordination number of `Na^(+)` is 6 or4.

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Radius of` Na^(+)`= 95 pm
Radius of` CI_(-)`=181 pm
Radius ratio, `r_(+)/r=(r(Na^(+)))/(r(CI^(-)))=95/181=0.524`
The radius ratio lies between 0.414-0.732. Hence, `Na^(+)` ions prefer to occupy octahefral holeshaving coordination number 6.
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