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(a) Complete the following chemical equ...

(a) Complete the following chemical equations:
(i) ` Cr_(2) O_(7)^(2-) (aq) + H_(2) S(g) + H^(+) (aq) to `
(ii) ` Cu^(2+)(aq) + I^(-) (aq) to `
(b) How would you account for the following :
(i) The oxidising power of oxoanions are in the order `VO_(2)^(+) lt Cr_(2)O_(7)^(2-) lt Mn O_(4)^(-) `
(ii) The third ionization enthalpy of manganess (Z = 25) is exceptionally high.
(iii) `Cr^(2+)` is a stronger reducing agent than `Fe^(2+)`.

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### Step-by-Step Solution #### Part (a): Complete the following chemical equations **(i)** The first equation is: \[ \text{Cr}_2\text{O}_7^{2-} (aq) + \text{H}_2\text{S} (g) + \text{H}^+ (aq) \rightarrow \] To balance this redox reaction, we need to identify the oxidation and reduction half-reactions. ...
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(a) Complete the following chemical equations : (i) Cr_(2)O_(7)^(2-)(aq)+H_(2)S(g)+H^(+)(aq)to (ii) Cu^(2+)(aq)+I^(-)(aq)to (b) How would you account for the following: (i) The oxidising power of oxoanions are in the order VO_(2)^(+)lt Cr_(2)O_(7)^(2-)lt MnO_(4)^(-) . (ii) The third ionisation enthalpy of manganese (Z = 25) is exceptionally high. (iii) Cr^(2+) is a stronger reducing agent than Fe^(2+) .

(a) Complete the following chemical equation: (i) Cr_(2)O_(7)^(2-)(aq)+H_(2)S(g)+H^(+)(aq) to , (ii) Cu^(2+)(aq)+I^(-)(aq) to (b) How would you account for the following: (i)The oxidising power of oxoanion are in the order VO_(2)^(+)ltCr_(2)O_(7)^(2-)ltMnO_(4)^(-) . (ii) The third ionization enthalpy of manganese (Z=25) is exceptionally high. (iii) Cr^(2+) is a stronger reducing agent than Fe^(2+) . Or (a) Complete the following chemical equation: (i) MnO_(4)^(-)(aq)+s_(2)O_(3)^(2-)(aq)+H_(2)O(I) to (ii) Cr_(2)O_(7)^(2-)(aq)+Fe^(2+)(aq)+H^(+)(aq) to (b) Explain the following observation: (i) La^(3+)(Z=57) and Lu^(3+)(Z=71) do not show any colour in solutions. (ii) Among the divalent cation in the first series of transition elements, manganese exhibits the maximum paramagnetism. (iii) Cu^(+) ion is not known in aqueous solutions.

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