Home
Class 12
CHEMISTRY
For a first order reaction, show that th...

For a first order reaction, show that the time required for `99%` completion is twice the time required for the completion of `90%` of reaction.

Text Solution

Verified by Experts

For `1^(st)` order reaction
`k=(2.303)/(t)log""(a)/(a-x)" "[a to "initial conc."a -x to "remaining conc." x to "reacted"]`
`t99%=(2.303)/(k)log""(100)/(100-99)`
`t99%=(2.303)/(k)log10^(2)`
`t99%=(2.303)/(k)xx2xx1" "[log10=1]`
`t99%=(2.303)/(k)xx2" "...(i)`
`t99%=(2.303)/(k)xxlog 10`
`t99%=(2.303)/(k)" "...(ii)[log10=I]`
From equation (i) and (ii)
`t99%=2xxt920%`
Promotional Banner

Topper's Solved these Questions

  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise [SET-I]|74 Videos
  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise [SET-II]|10 Videos
  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise Delhi Board : Set - III|7 Videos
  • SAMPLE PAPER 2019

    XII BOARDS PREVIOUS YEAR|Exercise SECTION: D|1 Videos

Similar Questions

Explore conceptually related problems

(a) For a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction. (b) Rate constant 'K' of a reaction varies with temperature 'T' according to the equation : logK=logA-E_a/(2.303R)(1/T) Where E_a is the activation energy. When a graph is plotted for log k Vs 1/(T) a straight line with a slope of -4250 K is obtained. Calculate E_a for the reaction. ( R=8.314JK^(-1)mol^(-1) )

Show that for a first order reaction, time required for 99.99% of the reaction to take place is 10 times the time required for the completion of half of the reaction.

For a first order reaction, if the time taken for completion of 50% of the reaction is t second, the time required for completion of 99.9% of the reaction is nt . Find the value of n?

Show that in case of a first order reaction, the time required for 99.9% of the reaction to take place is ten times that required for half of the reaction.

For a 1^("st") order reaction, time required for completion of 99% reaction is 10 min. Calculate time required for completion of 99.9% (in min.)

A first order reaction takes 100 min for completion of 60 % of reaction ,The time eequired for completion of 90% of the reaction is

XII BOARDS PREVIOUS YEAR-XII BOARDS-[SET-1]
  1. An element exists in bcc lattice with a cell edge of 288 pm. Calculate...

    Text Solution

    |

  2. Calculate Delta(r)G^(@) and log K(c) for the following reaction at 29...

    Text Solution

    |

  3. For a first order reaction, show that the time required for 99% comple...

    Text Solution

    |

  4. Explain the following phenomenon given reason : (i) Tnndall effect. ...

    Text Solution

    |

  5. (a) Write the principle involved in the following : {:((i)"Zone refi...

    Text Solution

    |

  6. A mixed oxide of iron and chromium is fused with sodium carbonate in f...

    Text Solution

    |

  7. (a) Give reasons for the following : (i) Compounds of transition ele...

    Text Solution

    |

  8. For the complex ion [F(en)(2)CI(2)]^(+) write the hybridization type a...

    Text Solution

    |

  9. (a) Account for the following : (i) Electrophilic substitution react...

    Text Solution

    |

  10. (a) Why phenol is more acidic than than ethanol ? (b) Write the mech...

    Text Solution

    |

  11. Identify A, B and C in the following reactions : (i) CH(3)CH(2)Clove...

    Text Solution

    |

  12. (a) Why water soluble vitamins must be supplied regularly in the dite ...

    Text Solution

    |

  13. (i) Name a substance which can be used as an antiseptic as well as dis...

    Text Solution

    |

  14. Once there was heavy downpour for about 3 hours in the early morning. ...

    Text Solution

    |

  15. (a) Explain why on addition of 1 mole glucose to 1 litre water the bol...

    Text Solution

    |

  16. (a) Define the following terms : {:((i)"Ideal solution",(ii)"Osmitic...

    Text Solution

    |

  17. (a) When concentrated sulphuric acid was added to an unknown salt pres...

    Text Solution

    |

  18. Account for the following (i) Reducing character decreases from SO(2...

    Text Solution

    |

  19. (a) Account for the following : (i) Propanal is more reactive than p...

    Text Solution

    |

  20. Write structure of A, B C and D in the following eactin sequence : {...

    Text Solution

    |