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Write down the IUPAC names of the follow...

Write down the IUPAC names of the following complexes and also give stereochemistry and magnetic moment of the complexes :
(i) `[Co(NH_(3))_(5)Cl]CL_(2)`
`[CrCl_(3)(py)_(3)]`
(iii) `k_(4)[Mn(CN)_(6)]`
(At. Nos. Cr=24, Mn=25, Co=27, py=pyridine)

Text Solution

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(i) Penta ammine chlorido cobalt (ii) chloride `d^(2)SP^(3)`, octahedral , diamagnetic.
(iii) Potassium hexcyano manganate (ii) `d^(2)SP^(3)` octahedral paramagnetic .
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