Home
Class 12
CHEMISTRY
An alcohol [A] with molecules formula (C...

An alcohol [A] with molecules formula `(C_(4)H_(10)O)` o oxidation with aciddified potassium dichromate gives acid [B] `(C_(4)H_(8)O_(2))`. Compound [A] when dehydrated with conc. `H_(2)SO_(4)` at `443 K` gives compound [C]. Treatment of [C] with aqueous `H_(2)SO_(4)` gives compound [D] `(C_(4)H_(10)O)` which is an isomer of [A]. compound [D] is resistant to oxidation but compound [A]can be easily oxidised. Identify [A], [B], [C] and [D]. Name the type of isomerism exhibited by [A] and [D].

Text Solution

Verified by Experts

`A :CH_(3)-overset(underset(|)(CH_(3)))(CH)-CH_(2)-OH " " B : CH_(3)-overset(underset(|)(CH_(3)))(CH)-COOH`
`C :CH_(3)-overset(underset(|)(CH_(3)))(CH)-CH_(2)=CH_(2) " " D : CH_(3)-overset(underset(|)(CH_(3)))underset(overset(|)(CH_(3)))(C)-CH_(3)`
A and D are position isomers.
Promotional Banner

Topper's Solved these Questions

  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise IMPORTANT QUESTIONS FOR PRACTICE CHEMISTRY (THEORY-XII) UNSOLVED)|42 Videos
  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise SET- I|35 Videos
  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise QUESTION PAPER (SECTION-B)|10 Videos
  • SAMPLE PAPER 2019

    XII BOARDS PREVIOUS YEAR|Exercise SECTION: D|1 Videos

Similar Questions

Explore conceptually related problems

A neutral organic compound X of molecualr formula C_(2)H_(6)O on oxidation with acidified potassium dichromate gives an acidic compound Y. Compound X reacts with Y on warming in the presence of conc H_(2)SO_(4) to give a sweet smelling substance Z.What are X,Y and Z?

An alcohol (A) C_4H_(10)O on oxidation with acidified K_2Cr_2O_7 gives a carboxylic acid (B) C_4H_8O_2 . (A) on treatment with conc. H_2SO_4 produces (C) C_4H_8 . (C) on treatment with dil. H_2SO_4 gives (D) C_4H_(10)O . The compound (D) is isomeric with compound (A). Compound (D) resist oxidation . What are (A) and (D) respectively ?

The compound F(C_(6)H_(12)O) on oxidative ozonolysis yirlds acetic acid and a compound (G) (C_(4)H_(8)O_(3)) . The new compound (G) on heating gives:

A compound [A] with molecular formula C_(4)H_(10)O reacts rapidly with metallic sodium but very slowly with Lucas reagent. When [A] treated with hot concentrated H_(2)SO_(4) , it gives a compound [B] C_(4)H_(8) which upon hydration with aqueous H_(2)SO_(4) forms a compound [C] with molecular formula C_(4)H_(10)O . The compound [C] is almost unert to metallic sodium but reacts rapidly with Lucas reagent. What are the compounds [A], [B] and [C] ? Explain the reaction involved.

A compound with molecular formula C_(6)H_(10)O_(4) on acylation with acetic anhydride gives a compound with molecular formula C_(12)H_(18)O_(8) . How many hydroxyl groups are present in the compound?

An alcohol ( A ) with molecular formula C_(4)H_(10)O on oxidation forms compound ( B ) C_(4)H_(8)O .The compound ( B ) gives iodoform test, but does not reduce ammonical silver nitrate, ( B ) on treatment with amalgamated zinc and HCl gives compound ( C ) C_(4)H_(10) . Identify A,B,C.

XII BOARDS PREVIOUS YEAR-XII BOARDS-QUESTION PAPER (SECTION-C)
  1. Niobium crystallises in body-centred cubic structure. If the atomic ra...

    Text Solution

    |

  2. Give reasons for the following : (a) When 2g of benzoic acid is diss...

    Text Solution

    |

  3. An alcohol [A] with molecules formula (C(4)H(10)O) o oxidation with ac...

    Text Solution

    |

  4. Which on of the following compounds will undergo faster hydrolysis rea...

    Text Solution

    |

  5. A compound is formed by the substitution of two chlorine atoms for two...

    Text Solution

    |

  6. Complete the following reactions :

    Text Solution

    |

  7. Give reasons for the following : (i) Use of aspartame as an artifici...

    Text Solution

    |

  8. (a) Name the branched chain component of starch. (b) Ribose in RNA a...

    Text Solution

    |

  9. Give three reactions of glucose which cannot be explained by its open ...

    Text Solution

    |

  10. The following data were obtained during the first order thermal decomp...

    Text Solution

    |

  11. Two reactions of the same order have equal pre exponential factors but...

    Text Solution

    |

  12. (a) A colloidal sol is prepared by the given method in figure. What is...

    Text Solution

    |

  13. Describe how the following steps can be carried out? (a) Recovery o...

    Text Solution

    |

  14. Explain the use of the following : (a) NaCN in Froth Floatation Method...

    Text Solution

    |

  15. Explain the following : (a) Out of Sc^(3+), Co^(2+) " and "Cr^(3+) "...

    Text Solution

    |

  16. A metal complex having composition Cr(NH(3))(4)CI(2)Br has been isolat...

    Text Solution

    |

  17. (a) Identify A-D (b) Distinguish between the following pair of compo...

    Text Solution

    |

  18. (a) Account for the following : (i) Direct nitration of aniline yie...

    Text Solution

    |

  19. (a) A cell is prepared by dipping a zinc rod in 1M zinc sulphate solut...

    Text Solution

    |

  20. (a) Apply Kohlrausch law of independent migration of ions, write the e...

    Text Solution

    |