Home
Class 12
CHEMISTRY
Determine the values of equilibrium cons...

Determine the values of equilibrium constant `(K_C) and DeltaG^o` for the following reaction :

Text Solution

Verified by Experts

The cell reaction is
`Ni(s)+2Ag^+(aq)toNi^(2+)(aq) +2Ag(s)`,
`DeltaG^o=-nFE^o`
`E^o=1.05V,n=2,f=96500C//"mol"`.
`DeltaG^o=-(2mol)xx(96500C//mol)xx(1.05V)`.
`=-202650 CV (1CV=1)`
`=-202650J`
Colculation of K in the from `DeltaG^o`,
`DeltaG^o=-202650J,R=8.314J//mol//K`.
`T=298k`.
`logK=(DeltaG^o)/(2.303RT)=(-202650J)/((2.303)xx(8.314J//mol//K)xx(298K))`
`=K=(-202650)/5705.84832=35.51`
`or K=0.35xx10^2`
Promotional Banner

Topper's Solved these Questions

  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise SET- II|10 Videos
  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise SET- III|10 Videos
  • XII BOARDS

    XII BOARDS PREVIOUS YEAR|Exercise IMPORTANT QUESTIONS FOR PRACTICE CHEMISTRY (THEORY-XII) UNSOLVED)|42 Videos
  • SAMPLE PAPER 2019

    XII BOARDS PREVIOUS YEAR|Exercise SECTION: D|1 Videos

Similar Questions

Explore conceptually related problems

Determine the values of equilibrium constant (K_(c)) and DeltaG^(@) for the reaction Ni(s)+2Ag^(+)(aq)rarrNi^(2+)(aq)+2Ag(s), E^(@)=1.05 V. ( "Given " 1F=96500"C mol"^(-1))

The progress of the reaction A hArr nB with time is persented in the figure given below: Determine a. The value of n. b. The equilibrium constant K. c. The initial rate of concentration of A.

At equilibrium, the rate of forward and backward reaction become equal and as a result concentration of each reactant and product becomes constant. The expression and numerical value of equilibrium constant depends upon the form of balanced chemical equation. If stoichiometry of the balanced chemical equation changes, the value of equilibrium constant changes. An equilibrium system for the reaction: N_2O_4(g) hArr 2NO_2(g) at 390 K. in a 5L flask contains 1.0 mol of NO_2 and 0.125 mol of N_2O_4 . What will be the effect on the value of K_c if more of N_2O_4 is added at equilibrium ?

The unit of equilibrium constant K_(c) for the reaction A+B hArr C would be

The relationship between equilibrium constants K_(p) "and" K_(c) for a gaseous reaction is:

How is DeltaG^(@) related to equilibrium constant?

At equilibrium, the rate of forward and backward reaction become equal and as a result concentration of each reactant and product becomes constant. The expression and numerical value of equilibrium constant depends upon the form of balanced chemical equation. If stoichiometry of the balanced chemical equation changes, the value of equilibrium constant changes. An equilibrium system for the reaction: N_2O_4(g) hArr 2NO_2(g) at 390 K. in a 5L flask contains 1.0 mol of NO_2 and 0.125 mol of N_2O_4 . What will be the value of K_c for the reaction: 1/2N_2O_4(g) hArr NO_2(g)

XII BOARDS PREVIOUS YEAR-XII BOARDS-SET- I
  1. Stereochemistry Of Polymers

    Text Solution

    |

  2. The chemistry of corrosion of iron is essentially an electrochemical p...

    Text Solution

    |

  3. Determine the values of equilibrium constant (KC) and DeltaG^o for the...

    Text Solution

    |

  4. Distinguish between 'rate expression' and 'rate constant' of a reactio...

    Text Solution

    |

  5. Give reason for : (i) SF6 is kinetically an inert substance. (ii...

    Text Solution

    |

  6. State reasons for each of the following : (i) All the P-Cl bonds in...

    Text Solution

    |

  7. Assign reasons for the following : (i) Copper (I) ion is not known i...

    Text Solution

    |

  8. Explain the following giving one example for each : (i) Reimer-Tiem...

    Text Solution

    |

  9. How would you obtain (i). Picric acid (2, 4, 6-trinitrophenol) from...

    Text Solution

    |

  10. What is essentially the difference between alpha-form of glucose and b...

    Text Solution

    |

  11. Describe what do you understand by the primary and secondary structure...

    Text Solution

    |

  12. Arrange the following polymers in increasing order of their intermolec...

    Text Solution

    |

  13. Silver crystallizes in face-centered cubic unit cell. Each side of thi...

    Text Solution

    |

  14. Nitrogen pentoxide decomposes according to equation : 2N2O5(g)to4NO...

    Text Solution

    |

  15. Explain how the phenomenon of pdsorption finds application in each of ...

    Text Solution

    |

  16. What are the different types of RNA formed in the cell ?

    Text Solution

    |

  17. Describe the principle behind each of the following processes : (i)...

    Text Solution

    |

  18. Complete the following chemical equations: (i) Na2CrO4+H2SO4to (ii...

    Text Solution

    |

  19. Write the name, stereochemistry and magnetic behaviour of the followin...

    Text Solution

    |

  20. Answer the following: (i) Haloalkanes easily dissolve in organic so...

    Text Solution

    |