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A complex of certain metal has the magne...

A complex of certain metal has the magnetic moment of 4.91 BM whereas another complex of the same metal with same oxidation state has zero magnetic moment. The metal ion could be :

A

`Co^(2+)`

B

`Mn^(2+)`

C

`Fe^(2+)`

D

`Fe^(3+)`

Text Solution

Verified by Experts

The correct Answer is:
C

`[overset(II)(Fe)(H_(2)O)_(6)]^(2-) n=4 and mu=4.91`
`[overset(II)(Fe)(CN)_(6)]^(4-) n=0 and mu=0`
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A complex of a certain metal ion has a magnetic moment of 4.90BM Another complex of the same metal ion in the same oxidation state has zero magnetic moment The central metal ion could be which of the following (a) Cr^(3+) ,(b) Mn^(3+) (c ) Fe^(2+) (d) Co^(2+) (ii) Refer to the question above if a metal ion has complex ion and with magnetic moments 4.90 and 2.8BM which one of these is the central metal ion (a) Cr^(3+) (b) Mn^(3+) , (c ) Fe^(2+) (d) Co^(2+) .

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RESONANCE-COORDINATION COMPOUNDS-Additional Problem for Self Practice (APSP) Part-I
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  2. If excess of AgNO(3) solution is added to 100mL of a 0.024 M solution ...

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  3. A complex of certain metal has the magnetic moment of 4.91 BM whereas ...

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  4. Oxidation number of Fe in violet coloured complex Na(4)[Fe(CN)(5)(NOS)...

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  5. Aqueous solution of nickel sulphate on treating with pyridine and then...

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  6. The IUPAC name of [Co(NH(3))(6)][Cr(C(2)O(4))(3)] is :

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  7. In the compound lithiumtetrahydroaluminate, the ligands is :

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  8. The oxidation numbe of Co in the complex ion is :

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  9. The magnitude of crystal field stabilisation energy (CFSE of Delta(1))...

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  10. Other than the X-ray difference , how could be the following pairs of ...

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  11. [Fe(en)(2)(H(2)O)(2)]^(2+) +en to " complex(X)". The correct statement...

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  12. Which of the following pairs will show the same magnetic moment ('spin...

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  13. What will be the 'spin only' magnetic moment of the complex formed whe...

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  14. Which of the following statement about Fe(CO)(5) is correct ?

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  15. The crystal field -splitting for Cr^(3+) ion in octahedral field chang...

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  16. Which of the following complex ion is not expected to absob visible li...

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  17. Of the following complex ions, the one that probably has the largest o...

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  18. The correct structure of Fe (CO)(5) is ?

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  19. Arrange the following in order of decreasing number of unpaired elect...

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  20. Match List-I (Complexes)with List-II (Hybridization ) of central atom ...

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