Home
Class 12
CHEMISTRY
The crystal field -splitting for Cr^(3+)...

The crystal field -splitting for `Cr^(3+)` ion in octahedral field changes for ligands `I^(-),H_(2)O,NH_(3),CN^(-)` and the increasing order is :

A

`I^(-) lt H_(2)O lt NH_(3) lt CN^(-)`

B

`CN^(-) lt I^(-) lt H_(2)O lt NH_(3)`

C

`CN^(-) lt NH_(3) lt H_(2)O lt I^(-)`

D

`NH_(3) lt H_(2)O lt I^(-) lt CN^(-)`

Text Solution

Verified by Experts

The correct Answer is:
A

(1) The crystal field-splitting for `Cr^(3+)` ion in octahedral field increases with increasing strength of ligands. This order given in (1) is according to spectrochemical series.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    RESONANCE|Exercise Additional Problem for Self Practice (APSP) Part-II|68 Videos
  • COORDINATION COMPOUNDS

    RESONANCE|Exercise Additional Problem for Self Practice (APSP) Part-III Subjected Question|7 Videos
  • COORDINATION COMPOUNDS

    RESONANCE|Exercise Exercise-3 Online Exam|22 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    RESONANCE|Exercise ORGANIC CHEMISTRY(Chemistry in every day life)|31 Videos
  • D & F BLOCK ELEMENTS

    RESONANCE|Exercise INORGANIC CHEMISTRY(d & f- Block Elments)|40 Videos

Similar Questions

Explore conceptually related problems

According to C.F.T, attraction between the central metal ion and ligands in a complex is purely electrostatic. The transition metal which forms the central atom cation in the complex is regarded as a positive ion. It is surrounded by negative ligands or neutral molecules which have a lone apir of electrons, if the ligand is a neutral molecule such as NH_(3) , the negative and of the dipole in the molecule is directed towards the metal cation. the electrons on the central metal ion are under repulsive forces from those on the ligands. thus the electrons occupy the d-orbitals remain away from the direction of approach ligands. ltBrgt Q. The crystal field-spliting order for Cr^(3+) cation is octahedral field for ligands CH_(3)COO^(-),NH_(3),H_(2)O,CN^(-) is:

Arrange NH_(4)^(+), H_(2)O, H_(3)O^(+), HF and OH^(-) in increasing order of acidic nature:

Crystal Field Splitting in Octahedral Complexes

The increasing order of crystal field splitting strength of the given ligands is

Correct order of crystal field splitting strength of ligands is

RESONANCE-COORDINATION COMPOUNDS-Additional Problem for Self Practice (APSP) Part-I
  1. A complex of certain metal has the magnetic moment of 4.91 BM whereas ...

    Text Solution

    |

  2. Oxidation number of Fe in violet coloured complex Na(4)[Fe(CN)(5)(NOS)...

    Text Solution

    |

  3. Aqueous solution of nickel sulphate on treating with pyridine and then...

    Text Solution

    |

  4. The IUPAC name of [Co(NH(3))(6)][Cr(C(2)O(4))(3)] is :

    Text Solution

    |

  5. In the compound lithiumtetrahydroaluminate, the ligands is :

    Text Solution

    |

  6. The oxidation numbe of Co in the complex ion is :

    Text Solution

    |

  7. The magnitude of crystal field stabilisation energy (CFSE of Delta(1))...

    Text Solution

    |

  8. Other than the X-ray difference , how could be the following pairs of ...

    Text Solution

    |

  9. [Fe(en)(2)(H(2)O)(2)]^(2+) +en to " complex(X)". The correct statement...

    Text Solution

    |

  10. Which of the following pairs will show the same magnetic moment ('spin...

    Text Solution

    |

  11. What will be the 'spin only' magnetic moment of the complex formed whe...

    Text Solution

    |

  12. Which of the following statement about Fe(CO)(5) is correct ?

    Text Solution

    |

  13. The crystal field -splitting for Cr^(3+) ion in octahedral field chang...

    Text Solution

    |

  14. Which of the following complex ion is not expected to absob visible li...

    Text Solution

    |

  15. Of the following complex ions, the one that probably has the largest o...

    Text Solution

    |

  16. The correct structure of Fe (CO)(5) is ?

    Text Solution

    |

  17. Arrange the following in order of decreasing number of unpaired elect...

    Text Solution

    |

  18. Match List-I (Complexes)with List-II (Hybridization ) of central atom ...

    Text Solution

    |

  19. Which of the following complexes ionization isomerism ?

    Text Solution

    |

  20. Coordination numbe of Ni in [Ni(C(2)O(4))(3)]^(4-) is :

    Text Solution

    |