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What is//are not true abut phosphine (PH...

What is//are not true abut phosphine `(PH_(3))`?

A

It turns red litmus blue

B

It reacts with HCl (aq.) to give `PH_(4)Cl`

C

Phosphonium compounds are obtained when anhydrous phosphine reacts with anhydrous HBr or HI

D

It is prepared by hydrolysis of metal phosphides with acids

Text Solution

Verified by Experts

The correct Answer is:
A, B

(A) `PH_(3)` is a lewis base but is neutral towards red litmus
(B) It does not react with HCl (aq) or HI(aq). This is because water decomposes `PH_(4)X` formed to given back `PH_(3)`
(C) It reacts only with anhydrous HI or HBr
(D) `2Na_(3)P + 3H_(2)SO_(4) rarr 3Na_(2)SO_(4) + 2PH_(3) uarr, Ca_(3)P_(2) + 6HCl rarr 3CaCl_(2) + 2PH_(3)`
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