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An orange solid (A) on heating gives a g...

An orange solid (A) on heating gives a green residue (B), a colourless gas (C ) and water vapours. The dry gas (C ) on passing over heated Mg gave a white solid (D). (D) on reaction with water gave a gas (E) which formed black preciptate with mercurous nitrate solution.
Select the incorrect statement.

A

The central atom (s) of the anion of solid (A) has `sp^(3)` hybridisation

B

The orange solid (A) is diamagnetic in nature

C

The anion of organe solid (A) is oxidising in nature

D

All metal oxygen bond lengths are equal in anion of solid (A)

Text Solution

Verified by Experts

The correct Answer is:
D

`A = (NH_(4))_(2) Cr_(2)O_(7)` , all electrons are paired. So diamagnetic `(3d^(0) 4s^(0)) Cr_(2)O_(7)^(2-)` acts as strong oxidising agent in acidic medium
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An orange solid (A) on heating gives a green residue (B), a colourless gas (C ) and water vapours. The dry gas (C ) on passing over heated Mg gave a white solid (D). (D) on reaction with water gave a gas (E) which formed black preciptate with mercurous nitrate solution. The green residue (B) is :

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RESONANCE-NITROGEN & OXYGEN FAMILY-Part-III Practice Test-2 (JEE (Advanced Pattern))
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