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Alldehydes and Ketones react with NH(2)O...

Alldehydes and Ketones react with `NH_(2)OH` to form aldoximes and Ketoximes respectively. Configuration of these can be determined by Beckmann rearragement as that group migrates which is anti w.r.t -OH


The product (B) is :

A

`{:(CH_(2)-COOH),("|"),(CH_(2)-NH_(2)):}`

B

`NH_(2)-underset(CH_(3))underset(|)(CH)-COOH`

C

D

Text Solution

Verified by Experts

The correct Answer is:
A
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The smallest ketone and its next homologue are reacted with NH_(2)OH to form oxime.

In organic chemistry various reactions take place by rearrangements. These rearrangements can be classified on the basis of migratory group and its nature. One of the well-known rearrangement is the formation of N-substituted amides by rearrangement of aldoximes or ketoximes. This is known as Beckmann rearrangement. It is catalysed by various acidic reagents. The mechanism of this reaction is given as product, The product formed is :