Home
Class 12
CHEMISTRY
2KMnO(4)+5H(2)S+6H^(+)rarr2Mn^(2+)+2K^(+...

`2KMnO_(4)+5H_(2)S+6H^(+)rarr2Mn^(2+)+2K^(+)+5S+8H_(2)O`.
In the above reaction, how many electrons would be involved in the oxidaton of 1 mole of reduction?

A

Two

B

Five

C

Ten

D

One

Text Solution

AI Generated Solution

The correct Answer is:
To determine how many electrons are involved in the oxidation of 1 mole of reduction in the given redox reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Half-Reactions**: - The reaction involves potassium permanganate (KMnO₄) being reduced to Mn²⁺ and hydrogen sulfide (H₂S) being oxidized to sulfur (S). - The half-reactions can be written as: - Reduction: \( \text{KMnO}_4 \rightarrow \text{Mn}^{2+} + \text{K}^+ + 4\text{H}_2O \) - Oxidation: \( \text{H}_2S \rightarrow \text{S} + 2\text{H}^+ + 2e^- \) 2. **Balance the Reduction Half-Reaction**: - For the reduction of KMnO₄ to Mn²⁺, we need to balance the oxygen and hydrogen: - Add 4 water molecules to the right side: \[ \text{KMnO}_4 + 8\text{H}^+ + 5e^- \rightarrow \text{Mn}^{2+} + \text{K}^+ + 4\text{H}_2O \] - This half-reaction shows that 5 electrons are gained. 3. **Balance the Oxidation Half-Reaction**: - For the oxidation of H₂S to S, we balance the charges: - The balanced half-reaction is: \[ 5\text{H}_2S \rightarrow 5\text{S} + 10\text{H}^+ + 10e^- \] - This indicates that 10 electrons are lost. 4. **Combine the Half-Reactions**: - Since we have 2 moles of KMnO₄ and 5 moles of H₂S in the overall reaction, we can multiply the half-reactions accordingly: - The reduction half-reaction (for 2 moles of KMnO₄) gives us 10 electrons. - The oxidation half-reaction (for 5 moles of H₂S) also gives us 10 electrons. - The total balanced reaction is: \[ 2\text{KMnO}_4 + 5\text{H}_2S + 6\text{H}^+ \rightarrow 2\text{Mn}^{2+} + 2\text{K}^+ + 5\text{S} + 8\text{H}_2O \] 5. **Determine Electrons for 1 Mole of Reduction**: - Since the reduction of 2 moles of KMnO₄ involves 10 electrons, the oxidation of 1 mole of reduction (which corresponds to 1 mole of KMnO₄) would involve: \[ \frac{10 \text{ electrons}}{2} = 5 \text{ electrons} \] ### Final Answer: The number of electrons involved in the oxidation of 1 mole of reduction is **5 electrons**.
Promotional Banner

Topper's Solved these Questions

  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 2|50 Videos
  • REDOX REACTIONS

    ALLEN|Exercise EXERICSE - 3|30 Videos
  • REDOX REACTIONS

    ALLEN|Exercise Questions|24 Videos
  • Redox Reaction

    ALLEN|Exercise All Questions|15 Videos
  • s-Block element

    ALLEN|Exercise All Questions|13 Videos

Similar Questions

Explore conceptually related problems

KMnO_(4)+H_(2)O_(2) rarr Mn^(2+)-O_(2)

2MnO_(4)^(-) + 5H_(2)O_(2) + 6H^(+) rarr 2Z + 5O_(2) + 8H_(2)O Identify Z in the above reaction.

2MnO_(4)^(-)+5H_(2)O_(2)+6H^(-) rarr 2Z+5O_(2)+8H_(2)O . In this reaction Z is

In the reaction, KNmO_(4) + 16 HC1 rarr 5C1_(2) + 2KC1 + 8H_(2) O the reduction product is

PbS(s)+4H_(2)O_(2)(aq)toPbSO_(4)(s)+4H_(2)O(l) In the above reaction, H_(2)O_(2) acts as a/an_____agent.

In the following reaction 2MnO_(4^(-))+5H_(2)O_(2)^(18)+6H^(+)rarr2Mn^(2+) + 8H_(2)O+5O_(2) The radioactive oxygen will appear in :

In the reaction, 2KMnO_(4)+16HClrarr 5Cl_(2)+2MnCl_(2)+2KCl+8H_(2)O the reduction product is

ALLEN-REDOX REACTIONS-Exercise - 1
  1. In the reaction VO+Fe(2)O(3) rarr FeO+V(2)O(5), the eq.wt. of V(2)O(5)...

    Text Solution

    |

  2. In the reaction, I(2)+2S(2)O(3)^(2-) rarr 2I^(-)+S(4)O(6)^(2-). Eq...

    Text Solution

    |

  3. Molecular weight of KBrO(3) is M. What is its equivalent weight, if th...

    Text Solution

    |

  4. In the reaction A^(-n2)+xe^(-)rarrA^(-n1) . Here, x will be :

    Text Solution

    |

  5. What would be the equivalent weight of the reductant in the reaction :...

    Text Solution

    |

  6. The eq. wt. of Na(2)S(2)O(3) as reductant in the reaction, Na(2)S(2)...

    Text Solution

    |

  7. The equivalent weight of FeC(2)O(4) in the change FeC(2)O(4)rarrFe^(...

    Text Solution

    |

  8. What will be n-factor for Ba(MnO(4))(2) in acidic medium? (Where it be...

    Text Solution

    |

  9. The number of mole of oxalate ions oxidised by one mole of MnO(4)^(-) ...

    Text Solution

    |

  10. Oxidising product of substance Na(3)AsO(3) would be

    Text Solution

    |

  11. In a reaction, 4 mole of electrons are transferred to 1 mole of HNO(3)...

    Text Solution

    |

  12. Balance given following half reaction for the unbalanced whole reactio...

    Text Solution

    |

  13. Choose the set coefficients that correctly balances the following equa...

    Text Solution

    |

  14. In the reaction : MnO(4)^(-)+xH^(+)+n e^(-)rarrMn^(2+)+yH(2)O What is ...

    Text Solution

    |

  15. The number of electrons required to balanced the following equation- ...

    Text Solution

    |

  16. The molar mass of CuSO(4).5H(2)O is 249. Its equivalent mass in the re...

    Text Solution

    |

  17. 2KMnO(4)+5H(2)S+6H^(+)rarr2Mn^(2+)+2K^(+)+5S+8H(2)O. In the above re...

    Text Solution

    |

  18. The value of n in : MnO(4)^(-)+8H^(+)+n erarr Mn^(2+)+4H(2)O is

    Text Solution

    |

  19. What is the value of n in the following equation : Cr(OH)(4)^(-)+OH^...

    Text Solution

    |

  20. For the redox reaction Zn+NO(3)^(-)rarr Zn^(2+)+NH(4)^(-) is basic m...

    Text Solution

    |