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What is the value of n in the following ...

What is the value of n in the following equation :
`Cr(OH)_(4)^(-)+OH^(-) rarr CrO_(4)^(2-)+H_(2)O+n e`?

A

3

B

6

C

5

D

2

Text Solution

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The correct Answer is:
To find the value of \( n \) in the given redox reaction: \[ \text{Cr(OH)}_4^{-} + \text{OH}^{-} \rightarrow \text{CrO}_4^{2-} + \text{H}_2\text{O} + n e^{-} \] we will follow these steps: ### Step 1: Balance the Atoms First, we need to ensure that the number of atoms of each element is balanced on both sides of the equation. - **Chromium (Cr)**: There is 1 Cr on both sides. - **Oxygen (O)**: On the left, we have 4 from \(\text{Cr(OH)}_4^{-}\) and 1 from \(\text{OH}^{-}\), totaling 5 O. On the right, we have 4 from \(\text{CrO}_4^{2-}\) and 1 from \(\text{H}_2\text{O}\), totaling 5 O. So, O is balanced. - **Hydrogen (H)**: On the left, we have 4 from \(\text{Cr(OH)}_4^{-}\) and 1 from \(\text{OH}^{-}\), totaling 5 H. On the right, we have 2 from \(\text{H}_2\text{O}\). To balance H, we need to add 3 \(\text{H}^+\) ions to the right side. Now the equation looks like this: \[ \text{Cr(OH)}_4^{-} + \text{OH}^{-} \rightarrow \text{CrO}_4^{2-} + \text{H}_2\text{O} + 3 \text{H}^{+} + n e^{-} \] ### Step 2: Balance the Charges Next, we need to balance the charges on both sides of the equation. - **Left Side Charge**: - \(\text{Cr(OH)}_4^{-}\) has a charge of -1. - \(\text{OH}^{-}\) has a charge of -1. - Total charge on the left = \(-1 - 1 = -2\). - **Right Side Charge**: - \(\text{CrO}_4^{2-}\) has a charge of -2. - \(\text{H}_2\text{O}\) is neutral (0). - \(3 \text{H}^{+}\) has a charge of +3. - The charge from the electrons is \(-n\). - Total charge on the right = \(-2 + 3 - n = 1 - n\). ### Step 3: Set Up the Charge Balance Equation Now we set the charges equal to each other: \[ -2 = 1 - n \] ### Step 4: Solve for \( n \) Rearranging the equation gives: \[ -2 - 1 = -n \] \[ -3 = -n \] \[ n = 3 \] ### Conclusion The value of \( n \) in the given redox reaction is \( 3 \). ---
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