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In the balanced equation MnO(4)^(-)+H^...

In the balanced equation
`MnO_(4)^(-)+H^(+)+C_(2)O_(4)^(2-)rarr Mn^(2+)+CO_(2)+H_(2)O`, the moles of `CO_(2)` formed are :-

A

2

B

4

C

5

D

10

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The correct Answer is:
To solve the question regarding the balanced equation \[ \text{MnO}_4^{-} + \text{H}^{+} + \text{C}_2\text{O}_4^{2-} \rightarrow \text{Mn}^{2+} + \text{CO}_2 + \text{H}_2\text{O} \] we need to determine the moles of \(\text{CO}_2\) formed. We will do this by balancing the redox reaction step by step. ### Step 1: Identify the half-reactions The first step is to separate the reaction into oxidation and reduction half-reactions. - **Reduction half-reaction**: The manganese in \(\text{MnO}_4^{-}\) is reduced to \(\text{Mn}^{2+}\). - **Oxidation half-reaction**: The oxalate ion \(\text{C}_2\text{O}_4^{2-}\) is oxidized to \(\text{CO}_2\). ### Step 2: Write the reduction half-reaction The reduction half-reaction for manganese can be written as: \[ \text{MnO}_4^{-} + 8\text{H}^{+} + 5\text{e}^{-} \rightarrow \text{Mn}^{2+} + 4\text{H}_2\text{O} \] ### Step 3: Write the oxidation half-reaction The oxidation half-reaction for oxalate can be written as: \[ \text{C}_2\text{O}_4^{2-} \rightarrow 2\text{CO}_2 + 2\text{e}^{-} \] ### Step 4: Balance the electrons To balance the overall reaction, we need to ensure that the number of electrons lost in the oxidation half-reaction equals the number of electrons gained in the reduction half-reaction. The reduction half-reaction involves 5 electrons, while the oxidation half-reaction involves 2 electrons. To balance, we can multiply the oxidation half-reaction by 5 and the reduction half-reaction by 2: - **Reduction half-reaction** (multiplied by 2): \[ 2\text{MnO}_4^{-} + 16\text{H}^{+} + 10\text{e}^{-} \rightarrow 2\text{Mn}^{2+} + 8\text{H}_2\text{O} \] - **Oxidation half-reaction** (multiplied by 5): \[ 5\text{C}_2\text{O}_4^{2-} \rightarrow 10\text{CO}_2 + 10\text{e}^{-} \] ### Step 5: Combine the half-reactions Now, we can combine both half-reactions: \[ 2\text{MnO}_4^{-} + 16\text{H}^{+} + 5\text{C}_2\text{O}_4^{2-} \rightarrow 2\text{Mn}^{2+} + 10\text{CO}_2 + 8\text{H}_2\text{O} \] ### Step 6: Determine the moles of \(\text{CO}_2\) From the balanced equation, we can see that for every 5 moles of \(\text{C}_2\text{O}_4^{2-}\) that react, 10 moles of \(\text{CO}_2\) are produced. Thus, the moles of \(\text{CO}_2\) formed are **10 moles**. ### Summary The balanced reaction shows that 10 moles of \(\text{CO}_2\) are produced when the reaction occurs. ---
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ALLEN-REDOX REACTIONS-EXERICSE - 2
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