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Which one is the oxidising agent in the ...

Which one is the oxidising agent in the reaction given below
`2CrO_(4)^(2-)+2H^(+)rarrCr_(2)O_(7)^(-2)+H_(2)O`

A

`H^(+)`

B

`Cr_(2)O_(7)^(-2)`

C

`Cr^(++)`

D

None

Text Solution

AI Generated Solution

The correct Answer is:
To determine the oxidizing agent in the reaction: \[ 2CrO_4^{2-} + 2H^+ \rightarrow Cr_2O_7^{2-} + H_2O \] we will analyze the oxidation states of the elements involved, particularly chromium (Cr) and hydrogen (H). ### Step 1: Assign Oxidation States - In \( CrO_4^{2-} \): - Oxygen (O) has an oxidation state of -2. - Let the oxidation state of chromium (Cr) be \( x \). - The equation for the oxidation state is: \[ x + 4(-2) = -2 \implies x - 8 = -2 \implies x = +6 \] - Thus, in \( CrO_4^{2-} \), Cr is in the +6 oxidation state. - In \( Cr_2O_7^{2-} \): - Again, let the oxidation state of chromium be \( y \). - The equation for the oxidation state is: \[ 2y + 7(-2) = -2 \implies 2y - 14 = -2 \implies 2y = 12 \implies y = +6 \] - Thus, in \( Cr_2O_7^{2-} \), Cr is also in the +6 oxidation state. - In \( H^+ \): - The oxidation state of hydrogen is +1. - In \( H_2O \): - The oxidation state of hydrogen is +1, and oxygen is -2. ### Step 2: Identify Changes in Oxidation States - The oxidation state of chromium does not change in this reaction; it remains +6 in both \( CrO_4^{2-} \) and \( Cr_2O_7^{2-} \). - The oxidation state of hydrogen changes from +1 in \( H^+ \) to 0 in \( H_2O \). ### Step 3: Determine the Oxidizing Agent - An oxidizing agent is a substance that gains electrons (is reduced) in a chemical reaction. - Here, \( H^+ \) is being reduced to \( H_2O \) (oxidation state changes from +1 to 0), indicating that \( H^+ \) is the species that is reduced. - Since \( H^+ \) is reduced, it acts as the oxidizing agent in this reaction. ### Conclusion The oxidizing agent in the reaction is \( H^+ \). ---
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