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The ratio of coefficient of HNO(3), Fe(N...

The ratio of coefficient of `HNO_(3), Fe(NO_(3))_(2)` and `NH_(4)NO_(3)` in the following redox reaction `Fe + HNO_(3) rarr Fe (NO_(3))_(2) + NH_(4)NO_(3) + H_(2)O`
are respectively

A

`1:10:4`

B

`10:4:1`

C

`4:10:1`

D

`10:1:4`

Text Solution

Verified by Experts

The correct Answer is:
B

`Fe+HNO_(3)rarrFe(NO_(3))_(2)+NH_(4)NO_(3)+H_(2)O`
Half reaction method :
`Fe rarr Fe^(2+)+2e^(-)..(1)xx4`
`NO_(3)^(-)+10H^(o+)+8e^(Theta)rarrNH_(4)^(o+)+3H_(2)O.....(2)`
Equation `(1)xx4+(2)`
`4Fe+NO_(3)^(-)+10H^(o+)rarr4fe^(2+)+NH_(4)^(o+)+3H_(2)O`
`"Add"^(n)` of spectator ion
`4Fe+10HNO_(3)rarr4Fe(NO_(3))_(2)+NH_(4)NO_(3)+3H_(2)O`
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