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When S(2)O(8)^(2-) oxidise Fe^(2+) then ...

When `S_(2)O_(8)^(2-)` oxidise `Fe^(2+)` then product formed is :-

A

`s_(2)O_(6)^(2-)`

B

`SO_(4)^(2-)`

C

`S_(2)O_(8)^(2-)`

D

`SO_(5)^(2-)`

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The correct Answer is:
To solve the question regarding the oxidation of \( S_2O_8^{2-} \) (peroxydisulfate ion) by \( Fe^{2+} \) (ferrous ion), we need to identify the products formed during this redox reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are \( S_2O_8^{2-} \) and \( Fe^{2+} \). 2. **Determine the Role of Each Reactant**: - \( S_2O_8^{2-} \) acts as an oxidizing agent because it can accept electrons. - \( Fe^{2+} \) acts as a reducing agent because it can donate electrons. 3. **Write the Half-Reactions**: - The oxidation half-reaction for \( Fe^{2+} \) is: \[ Fe^{2+} \rightarrow Fe^{3+} + e^- \] - The reduction half-reaction for \( S_2O_8^{2-} \) is: \[ S_2O_8^{2-} + 2e^- \rightarrow 2SO_4^{2-} \] 4. **Balance the Half-Reactions**: - The oxidation half-reaction shows that one \( Fe^{2+} \) ion loses one electron to become \( Fe^{3+} \). - The reduction half-reaction shows that \( S_2O_8^{2-} \) gains two electrons to form two \( SO_4^{2-} \) ions. 5. **Combine the Half-Reactions**: - Since two moles of \( Fe^{2+} \) are needed to provide the two electrons required for the reduction of one mole of \( S_2O_8^{2-} \), we can write: \[ 2Fe^{2+} + S_2O_8^{2-} \rightarrow 2Fe^{3+} + 2SO_4^{2-} \] 6. **Write the Final Balanced Equation**: - The final balanced equation for the reaction is: \[ 2Fe^{2+} + S_2O_8^{2-} \rightarrow 2Fe^{3+} + 2SO_4^{2-} \] ### Conclusion: The products formed when \( S_2O_8^{2-} \) oxidizes \( Fe^{2+} \) are \( Fe^{3+} \) and \( SO_4^{2-} \).
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